Origin of the stabilization of the metastable tetragonal high-pressure phase in SrCuO2 thin films grown on SrTiO3 substrates by pulsed laser deposition.

Saved in:
Bibliographic Details
Title: Origin of the stabilization of the metastable tetragonal high-pressure phase in SrCuO2 thin films grown on SrTiO3 substrates by pulsed laser deposition.
Authors: Mihailescu, C.N.1,2, Pasuk, I.3, Straticiuc, M.4, Nita, C.R.4, Pantelica, D.4, Giapintzakis, J.1 giapintz@ucy.ac.cy
Source: Applied Surface Science. Nov2014, Vol. 320, p852-857. 6p.
Subjects: Strontium compounds, Stabilizing agents, Metastable states, High pressure physics, Thin films, Pulsed laser deposition, Substrates (Materials science)
Abstract: In this work we have systematically investigated the evolution of structure and stoichiometry in SrCuO 2 films grown on TiO 2 -terminated SrTiO 3 substrates as a function of the substrate temperature. Depending on the growth temperature SrCuO 2 /SrTiO 3 films can exhibit either a pure tetragonal high-pressure phase, or a pure orthorhombic low-pressure phase, or a mixed phase. Our results indicate that at low substrate temperatures the non-equilibrium state of the growth process is responsible for the stabilization of the metastable tetragonal high-pressure structure in SrCuO 2 thin films grown on ( 0 0 1) SrTiO 3 substrates, whose lattice matches the metastable structure. In addition, at higher substrate temperatures thermodynamics become dominant over other factors and the SrCuO 2 thin films are stabilized in the thermodynamically stable orthorhombic phase. [ABSTRACT FROM AUTHOR]
Copyright of Applied Surface Science is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
FullText Text:
  Availability: 0
Header DbId: egs
DbLabel: Engineering Source
An: 99611067
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
PreciseRelevancyScore: 0
IllustrationInfo
Items – Name: Title
  Label: Title
  Group: Ti
  Data: Origin of the stabilization of the metastable tetragonal high-pressure phase in SrCuO2 thin films grown on SrTiO3 substrates by pulsed laser deposition.
– Name: Author
  Label: Authors
  Group: Au
  Data: <searchLink fieldCode="AR" term="%22Mihailescu%2C+C%2EN%2E%22">Mihailescu, C.N.</searchLink><relatesTo>1,2</relatesTo><br /><searchLink fieldCode="AR" term="%22Pasuk%2C+I%2E%22">Pasuk, I.</searchLink><relatesTo>3</relatesTo><br /><searchLink fieldCode="AR" term="%22Straticiuc%2C+M%2E%22">Straticiuc, M.</searchLink><relatesTo>4</relatesTo><br /><searchLink fieldCode="AR" term="%22Nita%2C+C%2ER%2E%22">Nita, C.R.</searchLink><relatesTo>4</relatesTo><br /><searchLink fieldCode="AR" term="%22Pantelica%2C+D%2E%22">Pantelica, D.</searchLink><relatesTo>4</relatesTo><br /><searchLink fieldCode="AR" term="%22Giapintzakis%2C+J%2E%22">Giapintzakis, J.</searchLink><relatesTo>1</relatesTo><i> giapintz@ucy.ac.cy</i>
– Name: TitleSource
  Label: Source
  Group: Src
  Data: <searchLink fieldCode="JN" term="%22Applied+Surface+Science%22">Applied Surface Science</searchLink>. Nov2014, Vol. 320, p852-857. 6p.
– Name: Subject
  Label: Subjects
  Group: Su
  Data: <searchLink fieldCode="DE" term="%22Strontium+compounds%22">Strontium compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Stabilizing+agents%22">Stabilizing agents</searchLink><br /><searchLink fieldCode="DE" term="%22Metastable+states%22">Metastable states</searchLink><br /><searchLink fieldCode="DE" term="%22High+pressure+physics%22">High pressure physics</searchLink><br /><searchLink fieldCode="DE" term="%22Thin+films%22">Thin films</searchLink><br /><searchLink fieldCode="DE" term="%22Pulsed+laser+deposition%22">Pulsed laser deposition</searchLink><br /><searchLink fieldCode="DE" term="%22Substrates+%28Materials+science%29%22">Substrates (Materials science)</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: In this work we have systematically investigated the evolution of structure and stoichiometry in SrCuO 2 films grown on TiO 2 -terminated SrTiO 3 substrates as a function of the substrate temperature. Depending on the growth temperature SrCuO 2 /SrTiO 3 films can exhibit either a pure tetragonal high-pressure phase, or a pure orthorhombic low-pressure phase, or a mixed phase. Our results indicate that at low substrate temperatures the non-equilibrium state of the growth process is responsible for the stabilization of the metastable tetragonal high-pressure structure in SrCuO 2 thin films grown on ( 0 0 1) SrTiO 3 substrates, whose lattice matches the metastable structure. In addition, at higher substrate temperatures thermodynamics become dominant over other factors and the SrCuO 2 thin films are stabilized in the thermodynamically stable orthorhombic phase. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Applied Surface Science is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
PLink https://search.ebscohost.com/login.aspx?direct=true&site=eds-live&db=egs&AN=99611067
RecordInfo BibRecord:
  BibEntity:
    Identifiers:
      – Type: doi
        Value: 10.1016/j.apsusc.2014.09.116
    Languages:
      – Code: eng
        Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 6
        StartPage: 852
    Subjects:
      – SubjectFull: Strontium compounds
        Type: general
      – SubjectFull: Stabilizing agents
        Type: general
      – SubjectFull: Metastable states
        Type: general
      – SubjectFull: High pressure physics
        Type: general
      – SubjectFull: Thin films
        Type: general
      – SubjectFull: Pulsed laser deposition
        Type: general
      – SubjectFull: Substrates (Materials science)
        Type: general
    Titles:
      – TitleFull: Origin of the stabilization of the metastable tetragonal high-pressure phase in SrCuO2 thin films grown on SrTiO3 substrates by pulsed laser deposition.
        Type: main
  BibRelationships:
    HasContributorRelationships:
      – PersonEntity:
          Name:
            NameFull: Mihailescu, C.N.
      – PersonEntity:
          Name:
            NameFull: Pasuk, I.
      – PersonEntity:
          Name:
            NameFull: Straticiuc, M.
      – PersonEntity:
          Name:
            NameFull: Nita, C.R.
      – PersonEntity:
          Name:
            NameFull: Pantelica, D.
      – PersonEntity:
          Name:
            NameFull: Giapintzakis, J.
    IsPartOfRelationships:
      – BibEntity:
          Dates:
            – D: 30
              M: 11
              Text: Nov2014
              Type: published
              Y: 2014
          Identifiers:
            – Type: issn-print
              Value: 01694332
          Numbering:
            – Type: volume
              Value: 320
          Titles:
            – TitleFull: Applied Surface Science
              Type: main
ResultId 1