View in EDS

NHC-amide donor ligands in rhodium complexes: Syntheses and characterisation.

Saved in:
Bibliographic Details
Title: NHC-amide donor ligands in rhodium complexes: Syntheses and characterisation.
Authors: Warsink, Stefan1 stefanwarsink@gmail.com, Venter, Johan A.1, Roodt, Andreas1
Source: Journal of Organometallic Chemistry. Jan2015, Vol. 775, p195-201. 7p.
Subjects: Rhodium compounds synthesis, Nitrogen, Heterocyclic compounds, Carbenes, Amides, Ligands (Chemistry), Metal complexes
Abstract: Rhodium(I) complexes bearing amide-functionalised NHC ligands were synthesized in high yields through various synthetic routes and from different metal precursors, showing the versatility of such systems. By changing the ancillary ligands on the rhodium from cyclooctadiene to carbonyls the coordination behaviour of the NHC-amide ligand could be influenced. When a more basic precursor was employed for complexation, bidentate behaviour with the amide in an anionic mode was observed. All reported complexes are synthesized in high yields and under ambient conditions, which shows their robustness. The monodentate rhodium(I) biscarbonyl NHC complexes were shown to be able to activate iodomethane. [ABSTRACT FROM AUTHOR]
Copyright of Journal of Organometallic Chemistry is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
FullText Text:
  Availability: 0
Header DbId: egs
DbLabel: Engineering Source
An: 99896474
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
PreciseRelevancyScore: 0
IllustrationInfo
Items – Name: Title
  Label: Title
  Group: Ti
  Data: NHC-amide donor ligands in rhodium complexes: Syntheses and characterisation.
– Name: Author
  Label: Authors
  Group: Au
  Data: <searchLink fieldCode="AR" term="%22Warsink%2C+Stefan%22">Warsink, Stefan</searchLink><relatesTo>1</relatesTo><i> stefanwarsink@gmail.com</i><br /><searchLink fieldCode="AR" term="%22Venter%2C+Johan+A%2E%22">Venter, Johan A.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Roodt%2C+Andreas%22">Roodt, Andreas</searchLink><relatesTo>1</relatesTo>
– Name: TitleSource
  Label: Source
  Group: Src
  Data: <searchLink fieldCode="JN" term="%22Journal+of+Organometallic+Chemistry%22">Journal of Organometallic Chemistry</searchLink>. Jan2015, Vol. 775, p195-201. 7p.
– Name: Subject
  Label: Subjects
  Group: Su
  Data: <searchLink fieldCode="DE" term="%22Rhodium+compounds+synthesis%22">Rhodium compounds synthesis</searchLink><br /><searchLink fieldCode="DE" term="%22Nitrogen%22">Nitrogen</searchLink><br /><searchLink fieldCode="DE" term="%22Heterocyclic+compounds%22">Heterocyclic compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Carbenes%22">Carbenes</searchLink><br /><searchLink fieldCode="DE" term="%22Amides%22">Amides</searchLink><br /><searchLink fieldCode="DE" term="%22Ligands+%28Chemistry%29%22">Ligands (Chemistry)</searchLink><br /><searchLink fieldCode="DE" term="%22Metal+complexes%22">Metal complexes</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Rhodium(I) complexes bearing amide-functionalised NHC ligands were synthesized in high yields through various synthetic routes and from different metal precursors, showing the versatility of such systems. By changing the ancillary ligands on the rhodium from cyclooctadiene to carbonyls the coordination behaviour of the NHC-amide ligand could be influenced. When a more basic precursor was employed for complexation, bidentate behaviour with the amide in an anionic mode was observed. All reported complexes are synthesized in high yields and under ambient conditions, which shows their robustness. The monodentate rhodium(I) biscarbonyl NHC complexes were shown to be able to activate iodomethane. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Journal of Organometallic Chemistry is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
PLink https://search.ebscohost.com/login.aspx?direct=true&site=eds-live&db=egs&AN=99896474
RecordInfo BibRecord:
  BibEntity:
    Identifiers:
      – Type: doi
        Value: 10.1016/j.jorganchem.2014.10.020
    Languages:
      – Code: eng
        Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 7
        StartPage: 195
    Subjects:
      – SubjectFull: Rhodium compounds synthesis
        Type: general
      – SubjectFull: Nitrogen
        Type: general
      – SubjectFull: Heterocyclic compounds
        Type: general
      – SubjectFull: Carbenes
        Type: general
      – SubjectFull: Amides
        Type: general
      – SubjectFull: Ligands (Chemistry)
        Type: general
      – SubjectFull: Metal complexes
        Type: general
    Titles:
      – TitleFull: NHC-amide donor ligands in rhodium complexes: Syntheses and characterisation.
        Type: main
  BibRelationships:
    HasContributorRelationships:
      – PersonEntity:
          Name:
            NameFull: Warsink, Stefan
      – PersonEntity:
          Name:
            NameFull: Venter, Johan A.
      – PersonEntity:
          Name:
            NameFull: Roodt, Andreas
    IsPartOfRelationships:
      – BibEntity:
          Dates:
            – D: 01
              M: 01
              Text: Jan2015
              Type: published
              Y: 2015
          Identifiers:
            – Type: issn-print
              Value: 0022328X
          Numbering:
            – Type: volume
              Value: 775
          Titles:
            – TitleFull: Journal of Organometallic Chemistry
              Type: main
ResultId 1