Effect of Particle Size on Magnetic Phase Coexistence in Nanocrystalline La0.4Bi0.3Sr0.3MnO3.

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Title: Effect of Particle Size on Magnetic Phase Coexistence in Nanocrystalline La0.4Bi0.3Sr0.3MnO3.
Authors: Souza, Anita D.1 (AUTHOR), Rayaprol, Sudhindra2 (AUTHOR), Murari, M. S.3 (AUTHOR), Daivajna, Mamatha D.1 (AUTHOR) mamatha.daijna@manipal.edu
Source: Journal of Superconductivity & Novel Magnetism. Dec2021, Vol. 34 Issue 12, p3319-3331. 13p.
Subject Terms: *Magnetic particles, *Metamagnetism, *Magnetic cores, *Magnetic susceptibility, *Magnetic materials, *Magnetization measurement
Abstract: Magnetic phase coexistence in the substituted perovskite compound, La0.4Bi0.3Sr0.3MnO3, is attributed to the spontaneous moment and a step-like metamagnetic transition observed in the magnetization measurements in its magnetically order state. The magnetism of samples reduced to nanometer sizes by the "top down" approach exhibits interesting changes with respect to the bulk, thus giving a handle in influencing the physical properties by reducing the particle size. The bulk sample orders ferromagnetically at TC = 295 K, whereas in nano-sized samples with particle sizes in the range of 21–30 nm, even though TC does not change, the transitions are suppressed. The nano-sized powder samples show a broad hump in the plot of magnetic susceptibility, signifying the possible disordered antiferromagnetic state. A systematic decrease in the magnitude of magnetization in nano-sized samples shows that the reduction in magnetic interaction could be attributed to the formation of a magnetic dead layer around the magnetic core. [ABSTRACT FROM AUTHOR]
Database: Energy & Power Source
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Items – Name: Title
  Label: Title
  Group: Ti
  Data: Effect of Particle Size on Magnetic Phase Coexistence in Nanocrystalline La<subscript>0.4</subscript>Bi<subscript>0.3</subscript>Sr<subscript>0.3</subscript>MnO<subscript>3</subscript>.
– Name: Author
  Label: Authors
  Group: Au
  Data: <searchLink fieldCode="AR" term="%22Souza%2C+Anita+D%2E%22">Souza, Anita D.</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Rayaprol%2C+Sudhindra%22">Rayaprol, Sudhindra</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Murari%2C+M%2E+S%2E%22">Murari, M. S.</searchLink><relatesTo>3</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Daivajna%2C+Mamatha+D%2E%22">Daivajna, Mamatha D.</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> mamatha.daijna@manipal.edu</i>
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  Data: <searchLink fieldCode="JN" term="%22Journal+of+Superconductivity+%26+Novel+Magnetism%22">Journal of Superconductivity & Novel Magnetism</searchLink>. Dec2021, Vol. 34 Issue 12, p3319-3331. 13p.
– Name: Subject
  Label: Subject Terms
  Group: Su
  Data: *<searchLink fieldCode="DE" term="%22Magnetic+particles%22">Magnetic particles</searchLink><br />*<searchLink fieldCode="DE" term="%22Metamagnetism%22">Metamagnetism</searchLink><br />*<searchLink fieldCode="DE" term="%22Magnetic+cores%22">Magnetic cores</searchLink><br />*<searchLink fieldCode="DE" term="%22Magnetic+susceptibility%22">Magnetic susceptibility</searchLink><br />*<searchLink fieldCode="DE" term="%22Magnetic+materials%22">Magnetic materials</searchLink><br />*<searchLink fieldCode="DE" term="%22Magnetization+measurement%22">Magnetization measurement</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Magnetic phase coexistence in the substituted perovskite compound, La0.4Bi0.3Sr0.3MnO3, is attributed to the spontaneous moment and a step-like metamagnetic transition observed in the magnetization measurements in its magnetically order state. The magnetism of samples reduced to nanometer sizes by the "top down" approach exhibits interesting changes with respect to the bulk, thus giving a handle in influencing the physical properties by reducing the particle size. The bulk sample orders ferromagnetically at TC = 295 K, whereas in nano-sized samples with particle sizes in the range of 21–30 nm, even though TC does not change, the transitions are suppressed. The nano-sized powder samples show a broad hump in the plot of magnetic susceptibility, signifying the possible disordered antiferromagnetic state. A systematic decrease in the magnitude of magnetization in nano-sized samples shows that the reduction in magnetic interaction could be attributed to the formation of a magnetic dead layer around the magnetic core. [ABSTRACT FROM AUTHOR]
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RecordInfo BibRecord:
  BibEntity:
    Identifiers:
      – Type: doi
        Value: 10.1007/s10948-021-06013-7
    Languages:
      – Code: eng
        Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 13
        StartPage: 3319
    Subjects:
      – SubjectFull: Magnetic particles
        Type: general
      – SubjectFull: Metamagnetism
        Type: general
      – SubjectFull: Magnetic cores
        Type: general
      – SubjectFull: Magnetic susceptibility
        Type: general
      – SubjectFull: Magnetic materials
        Type: general
      – SubjectFull: Magnetization measurement
        Type: general
    Titles:
      – TitleFull: Effect of Particle Size on Magnetic Phase Coexistence in Nanocrystalline La0.4Bi0.3Sr0.3MnO3.
        Type: main
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          Name:
            NameFull: Souza, Anita D.
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          Name:
            NameFull: Rayaprol, Sudhindra
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            NameFull: Murari, M. S.
      – PersonEntity:
          Name:
            NameFull: Daivajna, Mamatha D.
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          Dates:
            – D: 01
              M: 12
              Text: Dec2021
              Type: published
              Y: 2021
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              Value: 15571939
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              Value: 34
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              Value: 12
          Titles:
            – TitleFull: Journal of Superconductivity & Novel Magnetism
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