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Rheological characterization of potassium carbonate deep eutectic solvent (DES) based drilling mud.

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Title: Rheological characterization of potassium carbonate deep eutectic solvent (DES) based drilling mud.
Authors: Rasool, Muhammad Hammad1 (AUTHOR), Zamir, Asif1,2 (AUTHOR) asif.zamir@utp.edu.my, Elraies, Khaled A.1 (AUTHOR), Ahmad, Maqsood1 (AUTHOR), Ayoub, Muhammad3 (AUTHOR), Abbas, Muhammad Adeem1 (AUTHOR), Ali, Imtiaz1 (AUTHOR)
Source: Journal of Petroleum Exploration & Production Technology. Jul2022, Vol. 12 Issue 7, p1785-1795. 11p.
Subject Terms: *Drilling muds, *Potassium carbonate, *Slurry, *Drilling fluids, *Sustainable chemistry, *Rheology
Abstract: Different additives are added in the drilling mud to increase its efficiency in terms of its rheology and filtration properties. Recently, the application of ionic liquids (ILs) has been exploited by various investigators as a drilling additive for improving the mud rheology. The more recent studies have shown that imidazolium-based ionic liquids (the most used class of ionic liquids in drilling fluids) are toxic. Moreover, the advancement in green chemistry has put a big question mark on the greener nature of ionic liquids because they are non-biodegradable and generally very expensive. Deep eutectic solvents (DES) are the non-toxic and cheaper alternative of ionic liquids possessing the same qualities as of ILs. In our previous work, we used potassium carbonate and glycerol-based DES as a drilling fluid additive. We found that DES has successfully improved the mud rheology and filtration properties of the mud. In this current study, various characterizations have been conducted to understand the underlying mechanism behind DES as a rheology modifier. The characterization shows the improvement in rheology is due to the intercalation of DES between alumino-silicate layers and interaction of DES with clay which alters edge to face orientation of sodium bentonite and ultimately its dispersion behaviour. The addition of DES decreases average grain size and disperses the clay particles in mud slurry which reduce the overall permeability and porosity of the filter cake thus improving the filtration behaviour of the mud. Moreover, the behaviour of DES based mud is modelled at 25 °C and 100 °C which shows DES-based mud follows Herschel–Buckley model and exhibits shear thinning behaviour even at elevated temperature. [ABSTRACT FROM AUTHOR]
Database: Energy & Power Source
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Header DbId: enr
DbLabel: Energy & Power Source
An: 157262810
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  Group: Ti
  Data: Rheological characterization of potassium carbonate deep eutectic solvent (DES) based drilling mud.
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  Data: <searchLink fieldCode="AR" term="%22Rasool%2C+Muhammad+Hammad%22">Rasool, Muhammad Hammad</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Zamir%2C+Asif%22">Zamir, Asif</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<i> asif.zamir@utp.edu.my</i><br /><searchLink fieldCode="AR" term="%22Elraies%2C+Khaled+A%2E%22">Elraies, Khaled A.</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Ahmad%2C+Maqsood%22">Ahmad, Maqsood</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Ayoub%2C+Muhammad%22">Ayoub, Muhammad</searchLink><relatesTo>3</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Abbas%2C+Muhammad+Adeem%22">Abbas, Muhammad Adeem</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Ali%2C+Imtiaz%22">Ali, Imtiaz</searchLink><relatesTo>1</relatesTo> (AUTHOR)
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  Data: <searchLink fieldCode="JN" term="%22Journal+of+Petroleum+Exploration+%26+Production+Technology%22">Journal of Petroleum Exploration & Production Technology</searchLink>. Jul2022, Vol. 12 Issue 7, p1785-1795. 11p.
– Name: Subject
  Label: Subject Terms
  Group: Su
  Data: *<searchLink fieldCode="DE" term="%22Drilling+muds%22">Drilling muds</searchLink><br />*<searchLink fieldCode="DE" term="%22Potassium+carbonate%22">Potassium carbonate</searchLink><br />*<searchLink fieldCode="DE" term="%22Slurry%22">Slurry</searchLink><br />*<searchLink fieldCode="DE" term="%22Drilling+fluids%22">Drilling fluids</searchLink><br />*<searchLink fieldCode="DE" term="%22Sustainable+chemistry%22">Sustainable chemistry</searchLink><br />*<searchLink fieldCode="DE" term="%22Rheology%22">Rheology</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Different additives are added in the drilling mud to increase its efficiency in terms of its rheology and filtration properties. Recently, the application of ionic liquids (ILs) has been exploited by various investigators as a drilling additive for improving the mud rheology. The more recent studies have shown that imidazolium-based ionic liquids (the most used class of ionic liquids in drilling fluids) are toxic. Moreover, the advancement in green chemistry has put a big question mark on the greener nature of ionic liquids because they are non-biodegradable and generally very expensive. Deep eutectic solvents (DES) are the non-toxic and cheaper alternative of ionic liquids possessing the same qualities as of ILs. In our previous work, we used potassium carbonate and glycerol-based DES as a drilling fluid additive. We found that DES has successfully improved the mud rheology and filtration properties of the mud. In this current study, various characterizations have been conducted to understand the underlying mechanism behind DES as a rheology modifier. The characterization shows the improvement in rheology is due to the intercalation of DES between alumino-silicate layers and interaction of DES with clay which alters edge to face orientation of sodium bentonite and ultimately its dispersion behaviour. The addition of DES decreases average grain size and disperses the clay particles in mud slurry which reduce the overall permeability and porosity of the filter cake thus improving the filtration behaviour of the mud. Moreover, the behaviour of DES based mud is modelled at 25 °C and 100 °C which shows DES-based mud follows Herschel–Buckley model and exhibits shear thinning behaviour even at elevated temperature. [ABSTRACT FROM AUTHOR]
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RecordInfo BibRecord:
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      – Type: doi
        Value: 10.1007/s13202-021-01328-6
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      – Code: eng
        Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 11
        StartPage: 1785
    Subjects:
      – SubjectFull: Drilling muds
        Type: general
      – SubjectFull: Potassium carbonate
        Type: general
      – SubjectFull: Slurry
        Type: general
      – SubjectFull: Drilling fluids
        Type: general
      – SubjectFull: Sustainable chemistry
        Type: general
      – SubjectFull: Rheology
        Type: general
    Titles:
      – TitleFull: Rheological characterization of potassium carbonate deep eutectic solvent (DES) based drilling mud.
        Type: main
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            NameFull: Rasool, Muhammad Hammad
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            NameFull: Zamir, Asif
      – PersonEntity:
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            NameFull: Elraies, Khaled A.
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            NameFull: Ahmad, Maqsood
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            NameFull: Ayoub, Muhammad
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            NameFull: Abbas, Muhammad Adeem
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            NameFull: Ali, Imtiaz
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            – D: 01
              M: 07
              Text: Jul2022
              Type: published
              Y: 2022
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              Value: 12
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              Value: 7
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            – TitleFull: Journal of Petroleum Exploration & Production Technology
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