Demineralization strategies of carbon black derived from pyrolysis of waste tires.
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| Title: | Demineralization strategies of carbon black derived from pyrolysis of waste tires. |
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| Authors: | Ferrer, Victor1,2 (AUTHOR) vjfv1975@gmail.com, Grandón, Héctor1 (AUTHOR) hgrandonu@gmail.com, Segura, Cristina1 (AUTHOR) c.segura@udt.cl, Flores, Mauricio1 (AUTHOR) m.flores@udt.cl |
| Source: | Journal of Material Cycles & Waste Management. Jan2025, Vol. 27 Issue 1, p408-419. 12p. |
| Subject Terms: | *Pyrolytic graphite, *Manufacturing processes, *Particle size distribution, *Materials management, *Demineralization, *Waste tires |
| Abstract: | The pyrolysis of waste tires offers an environmentally friendly solution to the global tire waste problem. Pyrolytic carbon black (PCB) is an important by-product that can be reintroduced into industrial processes. This study aimed to improve the commercial viability of PCB by reducing its ash content. Pyrolysis was optimized at 420 °C for 4 h with a nitrogen flow rate of 1 L min-1. Demineralization, crucial for minimizing ash, was carried out using acid and alkali treatments (H2SO4, HNO3, HCl, NaOH). Two demineralization strategies were tested, one using fresh acid for three cycles and the other reusing the solution. The most effective method used 1 M HNO3 at 80 °C for 1 h, reducing the ash content to 1.7%. The demineralized PCB (PCBd) had improved properties, including a BET surface area of 74 m2 g-1, an iodine number of 57 mg g-1, and a particle size distribution up to 140 nm, comparable to commercial carbon blacks. These results highlight the potential of PCBd as a sustainable alternative for tire management and material production. [ABSTRACT FROM AUTHOR] |
| Database: | Energy & Power Source |
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| Header | DbId: enr DbLabel: Energy & Power Source An: 182152440 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
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| Items | – Name: Title Label: Title Group: Ti Data: Demineralization strategies of carbon black derived from pyrolysis of waste tires. – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22Ferrer%2C+Victor%22">Ferrer, Victor</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<i> vjfv1975@gmail.com</i><br /><searchLink fieldCode="AR" term="%22Grandón%2C+Héctor%22">Grandón, Héctor</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> hgrandonu@gmail.com</i><br /><searchLink fieldCode="AR" term="%22Segura%2C+Cristina%22">Segura, Cristina</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> c.segura@udt.cl</i><br /><searchLink fieldCode="AR" term="%22Flores%2C+Mauricio%22">Flores, Mauricio</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> m.flores@udt.cl</i> – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22Journal+of+Material+Cycles+%26+Waste+Management%22">Journal of Material Cycles & Waste Management</searchLink>. Jan2025, Vol. 27 Issue 1, p408-419. 12p. – Name: Subject Label: Subject Terms Group: Su Data: *<searchLink fieldCode="DE" term="%22Pyrolytic+graphite%22">Pyrolytic graphite</searchLink><br />*<searchLink fieldCode="DE" term="%22Manufacturing+processes%22">Manufacturing processes</searchLink><br />*<searchLink fieldCode="DE" term="%22Particle+size+distribution%22">Particle size distribution</searchLink><br />*<searchLink fieldCode="DE" term="%22Materials+management%22">Materials management</searchLink><br />*<searchLink fieldCode="DE" term="%22Demineralization%22">Demineralization</searchLink><br />*<searchLink fieldCode="DE" term="%22Waste+tires%22">Waste tires</searchLink> – Name: Abstract Label: Abstract Group: Ab Data: The pyrolysis of waste tires offers an environmentally friendly solution to the global tire waste problem. Pyrolytic carbon black (PCB) is an important by-product that can be reintroduced into industrial processes. This study aimed to improve the commercial viability of PCB by reducing its ash content. Pyrolysis was optimized at 420 °C for 4 h with a nitrogen flow rate of 1 L min-1. Demineralization, crucial for minimizing ash, was carried out using acid and alkali treatments (H2SO4, HNO3, HCl, NaOH). Two demineralization strategies were tested, one using fresh acid for three cycles and the other reusing the solution. The most effective method used 1 M HNO3 at 80 °C for 1 h, reducing the ash content to 1.7%. The demineralized PCB (PCBd) had improved properties, including a BET surface area of 74 m2 g-1, an iodine number of 57 mg g-1, and a particle size distribution up to 140 nm, comparable to commercial carbon blacks. These results highlight the potential of PCBd as a sustainable alternative for tire management and material production. [ABSTRACT FROM AUTHOR] |
| PLink | https://search.ebscohost.com/login.aspx?direct=true&site=eds-live&db=enr&AN=182152440 |
| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.1007/s10163-024-02120-4 Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 12 StartPage: 408 Subjects: – SubjectFull: Pyrolytic graphite Type: general – SubjectFull: Manufacturing processes Type: general – SubjectFull: Particle size distribution Type: general – SubjectFull: Materials management Type: general – SubjectFull: Demineralization Type: general – SubjectFull: Waste tires Type: general Titles: – TitleFull: Demineralization strategies of carbon black derived from pyrolysis of waste tires. Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Ferrer, Victor – PersonEntity: Name: NameFull: Grandón, Héctor – PersonEntity: Name: NameFull: Segura, Cristina – PersonEntity: Name: NameFull: Flores, Mauricio IsPartOfRelationships: – BibEntity: Dates: – D: 01 M: 01 Text: Jan2025 Type: published Y: 2025 Identifiers: – Type: issn-print Value: 14384957 Numbering: – Type: volume Value: 27 – Type: issue Value: 1 Titles: – TitleFull: Journal of Material Cycles & Waste Management Type: main |
| ResultId | 1 |