Mineral chemistry of the Geyer SW tin skarn deposit: understanding variable fluid/rock ratios and metal fluxes.

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Title: Mineral chemistry of the Geyer SW tin skarn deposit: understanding variable fluid/rock ratios and metal fluxes.
Authors: Meyer, Nicolas1 (AUTHOR) nicolas.meyer@uni-tuebingen.de, Burisch, Mathias2 (AUTHOR) burisch@mines.edu, Gutzmer, Jens3 (AUTHOR), Krause, Joachim3 (AUTHOR), Scheibert, Henning4 (AUTHOR), Markl, Gregor1 (AUTHOR)
Source: Mineralium Deposita. Jan2025, Vol. 60 Issue 1, p85-111. 27p.
Subject Terms: *Sulfide minerals, *Chlorite minerals, *Earth sciences, *Cassiterite, *Sphene, *Garnet, *Trace elements
Abstract: The Geyer tin skarn in the Erzgebirge, Germany, comprises an early skarnoid stage (stage I, ~ 320 Ma) and a younger metasomatic stage (stage II, ~ 305 Ma), but yet, the source and distribution of Sn and the physicochemical conditions of skarn alteration were not constrained. Our results illustrate that contact metamorphic skarnoids of stage I contain only little Sn. REE patterns and elevated concentrations of HFSE indicate that garnet, titanite and vesuvianite of stage I formed under rock-buffered conditions (low fluid/rock ratios). Prograde assemblages of stage II, in contrast, contain two generations of stanniferous garnet, titanite-malayaite and vesuvianite. Oscillation between rock-buffered and fluid-buffered conditions are marked by variable concentrations of HFSE, W, In, and Sn in metasomatic garnet. Trace and REE element signatures of minerals formed under high fluid/rock ratios appear to mimic the signature of the magmatic-hydrothermal fluid which gave rise to metasomatic skarn alteration. Concomitantly with lower fluid-rock ratio, tin was remobilized from Sn-rich silicates and re-precipitated as malayaite. Ingress of meteoric water and decreasing temperatures towards the end of stage II led to the formation of cassiterite, low-Sn amphibole, chlorite, and sulfide minerals. Minor and trace element compositions of cassiterite do not show much variation, even if host rock and gangue minerals vary significantly, suggesting a predominance of a magmatic-hydrothermal fluid and high fluid/rock ratios. The mineral chemistry of major skarn-forming minerals, hence, records the change in the fluid/rock ratio, and the arrival, distribution, and remobilization of tin by magmatic fluids in polyphase tin skarn systems. [ABSTRACT FROM AUTHOR]
Database: Energy & Power Source
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An: 182154314
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  Label: Title
  Group: Ti
  Data: Mineral chemistry of the Geyer SW tin skarn deposit: understanding variable fluid/rock ratios and metal fluxes.
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  Data: <searchLink fieldCode="AR" term="%22Meyer%2C+Nicolas%22">Meyer, Nicolas</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> nicolas.meyer@uni-tuebingen.de</i><br /><searchLink fieldCode="AR" term="%22Burisch%2C+Mathias%22">Burisch, Mathias</searchLink><relatesTo>2</relatesTo> (AUTHOR)<i> burisch@mines.edu</i><br /><searchLink fieldCode="AR" term="%22Gutzmer%2C+Jens%22">Gutzmer, Jens</searchLink><relatesTo>3</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Krause%2C+Joachim%22">Krause, Joachim</searchLink><relatesTo>3</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Scheibert%2C+Henning%22">Scheibert, Henning</searchLink><relatesTo>4</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Markl%2C+Gregor%22">Markl, Gregor</searchLink><relatesTo>1</relatesTo> (AUTHOR)
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  Data: <searchLink fieldCode="JN" term="%22Mineralium+Deposita%22">Mineralium Deposita</searchLink>. Jan2025, Vol. 60 Issue 1, p85-111. 27p.
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  Data: *<searchLink fieldCode="DE" term="%22Sulfide+minerals%22">Sulfide minerals</searchLink><br />*<searchLink fieldCode="DE" term="%22Chlorite+minerals%22">Chlorite minerals</searchLink><br />*<searchLink fieldCode="DE" term="%22Earth+sciences%22">Earth sciences</searchLink><br />*<searchLink fieldCode="DE" term="%22Cassiterite%22">Cassiterite</searchLink><br />*<searchLink fieldCode="DE" term="%22Sphene%22">Sphene</searchLink><br />*<searchLink fieldCode="DE" term="%22Garnet%22">Garnet</searchLink><br />*<searchLink fieldCode="DE" term="%22Trace+elements%22">Trace elements</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: The Geyer tin skarn in the Erzgebirge, Germany, comprises an early skarnoid stage (stage I, ~ 320 Ma) and a younger metasomatic stage (stage II, ~ 305 Ma), but yet, the source and distribution of Sn and the physicochemical conditions of skarn alteration were not constrained. Our results illustrate that contact metamorphic skarnoids of stage I contain only little Sn. REE patterns and elevated concentrations of HFSE indicate that garnet, titanite and vesuvianite of stage I formed under rock-buffered conditions (low fluid/rock ratios). Prograde assemblages of stage II, in contrast, contain two generations of stanniferous garnet, titanite-malayaite and vesuvianite. Oscillation between rock-buffered and fluid-buffered conditions are marked by variable concentrations of HFSE, W, In, and Sn in metasomatic garnet. Trace and REE element signatures of minerals formed under high fluid/rock ratios appear to mimic the signature of the magmatic-hydrothermal fluid which gave rise to metasomatic skarn alteration. Concomitantly with lower fluid-rock ratio, tin was remobilized from Sn-rich silicates and re-precipitated as malayaite. Ingress of meteoric water and decreasing temperatures towards the end of stage II led to the formation of cassiterite, low-Sn amphibole, chlorite, and sulfide minerals. Minor and trace element compositions of cassiterite do not show much variation, even if host rock and gangue minerals vary significantly, suggesting a predominance of a magmatic-hydrothermal fluid and high fluid/rock ratios. The mineral chemistry of major skarn-forming minerals, hence, records the change in the fluid/rock ratio, and the arrival, distribution, and remobilization of tin by magmatic fluids in polyphase tin skarn systems. [ABSTRACT FROM AUTHOR]
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RecordInfo BibRecord:
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      – Type: doi
        Value: 10.1007/s00126-024-01297-w
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      – Code: eng
        Text: English
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      Pagination:
        PageCount: 27
        StartPage: 85
    Subjects:
      – SubjectFull: Sulfide minerals
        Type: general
      – SubjectFull: Chlorite minerals
        Type: general
      – SubjectFull: Earth sciences
        Type: general
      – SubjectFull: Cassiterite
        Type: general
      – SubjectFull: Sphene
        Type: general
      – SubjectFull: Garnet
        Type: general
      – SubjectFull: Trace elements
        Type: general
    Titles:
      – TitleFull: Mineral chemistry of the Geyer SW tin skarn deposit: understanding variable fluid/rock ratios and metal fluxes.
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            NameFull: Meyer, Nicolas
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            NameFull: Burisch, Mathias
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            NameFull: Gutzmer, Jens
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            NameFull: Krause, Joachim
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            NameFull: Scheibert, Henning
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            – D: 01
              M: 01
              Text: Jan2025
              Type: published
              Y: 2025
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            – TitleFull: Mineralium Deposita
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