Thermo-kinetic analysis of co-pyrolysis of Platanus tree leaves with coals.

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Title: Thermo-kinetic analysis of co-pyrolysis of Platanus tree leaves with coals.
Authors: Shoaib, Muhammad1 (AUTHOR), Ku, Xiaoke1,2 (AUTHOR) xiaokeku@zju.edu.cn, Vasudev, Vikul1 (AUTHOR)
Source: International Journal of Coal Preparation & Utilization. 2026, Vol. 46 Issue 3, p775-792. 18p.
Subject Terms: *Pyrolysis kinetics, *Coal, *Thermodynamics, *Sycamores, *Activation energy, *Pyrolysis
Geographic Terms: Inner Mongolia (China)
Abstract: A thermo-kinetic study was conducted on the co-pyrolysis of Platanus tree leaves (PTL) with two different Chinese coals: Shanxi coal (SXC) and Inner Mongolia coal (IMC). The experiments were performed at various blending ratios and four different pyrolysis heating rates. The Friedman method was used to evaluate the kinetic parameters, while the Z(α) master plot approach was employed to identify the appropriate reaction model. The average activation energy values of PTL, SXC and IMC were 153.13, 275.12 and 323.04 kJ/mol, respectively. Increasing the proportion of PTL in the blends resulted in a decrease in the average activation energy values. Moreover, the thermodynamic parameters were also estimated. The values of enthalpy change and Gibbs free energy change were positive for each blend, indicating that the reactions were endothermic and non-spontaneous. The average entropy change was negative for most PTL-SXC blends, as well as for the PTL60+IMC40 and PTL80+IMC20 samples. Additionally, the synergistic effects during co-pyrolysis were also analyzed. [ABSTRACT FROM AUTHOR]
Database: Energy & Power Source
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DbLabel: Energy & Power Source
An: 192006236
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  Label: Title
  Group: Ti
  Data: Thermo-kinetic analysis of co-pyrolysis of Platanus tree leaves with coals.
– Name: Author
  Label: Authors
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  Data: <searchLink fieldCode="AR" term="%22Shoaib%2C+Muhammad%22">Shoaib, Muhammad</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Ku%2C+Xiaoke%22">Ku, Xiaoke</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<i> xiaokeku@zju.edu.cn</i><br /><searchLink fieldCode="AR" term="%22Vasudev%2C+Vikul%22">Vasudev, Vikul</searchLink><relatesTo>1</relatesTo> (AUTHOR)
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  Data: <searchLink fieldCode="JN" term="%22International+Journal+of+Coal+Preparation+%26+Utilization%22">International Journal of Coal Preparation & Utilization</searchLink>. 2026, Vol. 46 Issue 3, p775-792. 18p.
– Name: Subject
  Label: Subject Terms
  Group: Su
  Data: *<searchLink fieldCode="DE" term="%22Pyrolysis+kinetics%22">Pyrolysis kinetics</searchLink><br />*<searchLink fieldCode="DE" term="%22Coal%22">Coal</searchLink><br />*<searchLink fieldCode="DE" term="%22Thermodynamics%22">Thermodynamics</searchLink><br />*<searchLink fieldCode="DE" term="%22Sycamores%22">Sycamores</searchLink><br />*<searchLink fieldCode="DE" term="%22Activation+energy%22">Activation energy</searchLink><br />*<searchLink fieldCode="DE" term="%22Pyrolysis%22">Pyrolysis</searchLink>
– Name: SubjectGeographic
  Label: Geographic Terms
  Group: Su
  Data: <searchLink fieldCode="DE" term="%22Inner+Mongolia+%28China%29%22">Inner Mongolia (China)</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: A thermo-kinetic study was conducted on the co-pyrolysis of Platanus tree leaves (PTL) with two different Chinese coals: Shanxi coal (SXC) and Inner Mongolia coal (IMC). The experiments were performed at various blending ratios and four different pyrolysis heating rates. The Friedman method was used to evaluate the kinetic parameters, while the Z(α) master plot approach was employed to identify the appropriate reaction model. The average activation energy values of PTL, SXC and IMC were 153.13, 275.12 and 323.04 kJ/mol, respectively. Increasing the proportion of PTL in the blends resulted in a decrease in the average activation energy values. Moreover, the thermodynamic parameters were also estimated. The values of enthalpy change and Gibbs free energy change were positive for each blend, indicating that the reactions were endothermic and non-spontaneous. The average entropy change was negative for most PTL-SXC blends, as well as for the PTL60+IMC40 and PTL80+IMC20 samples. Additionally, the synergistic effects during co-pyrolysis were also analyzed. [ABSTRACT FROM AUTHOR]
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RecordInfo BibRecord:
  BibEntity:
    Identifiers:
      – Type: doi
        Value: 10.1080/19392699.2025.2480334
    Languages:
      – Code: eng
        Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 18
        StartPage: 775
    Subjects:
      – SubjectFull: Pyrolysis kinetics
        Type: general
      – SubjectFull: Coal
        Type: general
      – SubjectFull: Thermodynamics
        Type: general
      – SubjectFull: Sycamores
        Type: general
      – SubjectFull: Activation energy
        Type: general
      – SubjectFull: Pyrolysis
        Type: general
      – SubjectFull: Inner Mongolia (China)
        Type: general
    Titles:
      – TitleFull: Thermo-kinetic analysis of co-pyrolysis of Platanus tree leaves with coals.
        Type: main
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          Name:
            NameFull: Shoaib, Muhammad
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          Name:
            NameFull: Ku, Xiaoke
      – PersonEntity:
          Name:
            NameFull: Vasudev, Vikul
    IsPartOfRelationships:
      – BibEntity:
          Dates:
            – D: 01
              M: 03
              Text: 2026
              Type: published
              Y: 2026
          Identifiers:
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              Value: 19392699
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              Value: 46
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              Value: 3
          Titles:
            – TitleFull: International Journal of Coal Preparation & Utilization
              Type: main
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