Deposition of Oxidation-Resistant Hard Aluminide Layers on Hastelloy C-276: A Study on Microstructural and Kinetic Analysis.

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Title: Deposition of Oxidation-Resistant Hard Aluminide Layers on Hastelloy C-276: A Study on Microstructural and Kinetic Analysis.
Authors: Yener, Tuba1 (AUTHOR), Alaoğlu, Muhammed2,3 (AUTHOR), Atapek, Ş. Hakan4 (AUTHOR) hatapek@kocaeli.edu.tr, Aktaş Çelik, Gülşah4 (AUTHOR), Yener, S. Çağrı5,6 (AUTHOR), Özsoy, Neslihan7 (AUTHOR)
Source: Arabian Journal for Science & Engineering (Springer Science & Business Media B.V. ). Feb2026, Vol. 51 Issue 3, p3129-3144. 16p.
Subject Terms: *Protective coatings, *Diffusion control, *Chemical kinetics, *Microstructure, *Activation energy, *Alloys, *Nickel-aluminum alloys, *Surface coatings
Abstract: By aluminizing at varying temperature (600–700 °C) and time (2–6 h) cycles, defect-free, continuous and homogeneous thick Ni–Al deposition layers are obtained on Hastelloy C276 surface. Metallurgical analysis performed on surface/sub-surface indicates that NiAl3 and Ni2Al3 phases are the dominant phases within aluminide coatings (11–41 μm). Since the experimental aluminizing process is a diffusion-controlled process, the processing output with variable temperature and time parameters made it possible to study the process kinetics, and the process-specific activation energy is calculated as 51 kJ/mol. An equation is also derived from the regression model to estimate the coating thickness, and there is a good agreement between the coating thicknesses determined by the experimental and calculated values. The effect of temperature/time on the layer thickness is investigated with variance analysis. Although no significant change in the surface hardness value (~ 800 HV) is measured regardless of the layer thickness, an increase in the layer thickness over time on material surface processed at the lowest temperature causes a significant decrease in the oxidation rate due to the presence of a stable Al-rich oxide. All these findings reveal the lowest cost coating conditions that can reduce the chemical degradation of Hastelloy C276 caused by oxidation at high temperatures. [ABSTRACT FROM AUTHOR]
Database: Energy & Power Source
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  Label: Title
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  Data: Deposition of Oxidation-Resistant Hard Aluminide Layers on Hastelloy C-276: A Study on Microstructural and Kinetic Analysis.
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  Data: <searchLink fieldCode="AR" term="%22Yener%2C+Tuba%22">Yener, Tuba</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Alaoğlu%2C+Muhammed%22">Alaoğlu, Muhammed</searchLink><relatesTo>2,3</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Atapek%2C+Ş%2E+Hakan%22">Atapek, Ş. Hakan</searchLink><relatesTo>4</relatesTo> (AUTHOR)<i> hatapek@kocaeli.edu.tr</i><br /><searchLink fieldCode="AR" term="%22Aktaş+Çelik%2C+Gülşah%22">Aktaş Çelik, Gülşah</searchLink><relatesTo>4</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Yener%2C+S%2E+Çağrı%22">Yener, S. Çağrı</searchLink><relatesTo>5,6</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Özsoy%2C+Neslihan%22">Özsoy, Neslihan</searchLink><relatesTo>7</relatesTo> (AUTHOR)
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  Data: <searchLink fieldCode="JN" term="%22Arabian+Journal+for+Science+%26+Engineering+%28Springer+Science+%26+Business+Media+B%2EV%2E+%29%22">Arabian Journal for Science & Engineering (Springer Science & Business Media B.V. )</searchLink>. Feb2026, Vol. 51 Issue 3, p3129-3144. 16p.
– Name: Subject
  Label: Subject Terms
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  Data: *<searchLink fieldCode="DE" term="%22Protective+coatings%22">Protective coatings</searchLink><br />*<searchLink fieldCode="DE" term="%22Diffusion+control%22">Diffusion control</searchLink><br />*<searchLink fieldCode="DE" term="%22Chemical+kinetics%22">Chemical kinetics</searchLink><br />*<searchLink fieldCode="DE" term="%22Microstructure%22">Microstructure</searchLink><br />*<searchLink fieldCode="DE" term="%22Activation+energy%22">Activation energy</searchLink><br />*<searchLink fieldCode="DE" term="%22Alloys%22">Alloys</searchLink><br />*<searchLink fieldCode="DE" term="%22Nickel-aluminum+alloys%22">Nickel-aluminum alloys</searchLink><br />*<searchLink fieldCode="DE" term="%22Surface+coatings%22">Surface coatings</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: By aluminizing at varying temperature (600–700 °C) and time (2–6 h) cycles, defect-free, continuous and homogeneous thick Ni–Al deposition layers are obtained on Hastelloy C276 surface. Metallurgical analysis performed on surface/sub-surface indicates that NiAl3 and Ni2Al3 phases are the dominant phases within aluminide coatings (11–41 μm). Since the experimental aluminizing process is a diffusion-controlled process, the processing output with variable temperature and time parameters made it possible to study the process kinetics, and the process-specific activation energy is calculated as 51 kJ/mol. An equation is also derived from the regression model to estimate the coating thickness, and there is a good agreement between the coating thicknesses determined by the experimental and calculated values. The effect of temperature/time on the layer thickness is investigated with variance analysis. Although no significant change in the surface hardness value (~ 800 HV) is measured regardless of the layer thickness, an increase in the layer thickness over time on material surface processed at the lowest temperature causes a significant decrease in the oxidation rate due to the presence of a stable Al-rich oxide. All these findings reveal the lowest cost coating conditions that can reduce the chemical degradation of Hastelloy C276 caused by oxidation at high temperatures. [ABSTRACT FROM AUTHOR]
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RecordInfo BibRecord:
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      – Type: doi
        Value: 10.1007/s13369-025-10210-0
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      – Code: eng
        Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 16
        StartPage: 3129
    Subjects:
      – SubjectFull: Protective coatings
        Type: general
      – SubjectFull: Diffusion control
        Type: general
      – SubjectFull: Chemical kinetics
        Type: general
      – SubjectFull: Microstructure
        Type: general
      – SubjectFull: Activation energy
        Type: general
      – SubjectFull: Alloys
        Type: general
      – SubjectFull: Nickel-aluminum alloys
        Type: general
      – SubjectFull: Surface coatings
        Type: general
    Titles:
      – TitleFull: Deposition of Oxidation-Resistant Hard Aluminide Layers on Hastelloy C-276: A Study on Microstructural and Kinetic Analysis.
        Type: main
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            NameFull: Yener, Tuba
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            NameFull: Alaoğlu, Muhammed
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            NameFull: Atapek, Ş. Hakan
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            NameFull: Aktaş Çelik, Gülşah
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            NameFull: Yener, S. Çağrı
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            – D: 01
              M: 02
              Text: Feb2026
              Type: published
              Y: 2026
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              Value: 2193567X
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              Value: 51
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          Titles:
            – TitleFull: Arabian Journal for Science & Engineering (Springer Science & Business Media B.V. )
              Type: main
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