Decentralized Valorization of Associated Petroleum Gas via Modular Oxy-Combustion and Carbon Capture: A Scalable Strategy for Global Flaring Reduction.

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Title: Decentralized Valorization of Associated Petroleum Gas via Modular Oxy-Combustion and Carbon Capture: A Scalable Strategy for Global Flaring Reduction.
Authors: Chiriboga, Gonzalo1 (AUTHOR) wgchiriboga@uce.edu.ec, Núñez, Brandon1 (AUTHOR), Montero-Calderón, Carolina1 (AUTHOR), Gutiérrez, Christian1 (AUTHOR), Almeida, Carlos1 (AUTHOR), Vega, Michael A.1 (AUTHOR), Carvajal-Chávez, Ghem1 (AUTHOR)
Source: Energies (19961073). Apr2026, Vol. 19 Issue 8, p1949. 24p.
Subject Terms: *Oil fields, *Flare gas systems (Chemical engineering), *Carbon sequestration, *Energy consumption
Abstract: This study evaluates the technical feasibility of deploying containerized oxy-combustion power modules with integrated CO2 capture in remote Ecuadorian Amazon oil fields. Associated petroleum gas is conditioned with a 35 wt.% diethanolamine (DEA) sweetening stage specifically implemented to remove H2S and reduce acid-gas loading prior to combustion, improving fuel quality and protecting downstream equipment while increasing methane mole fraction for combustion. System efficiency is governed by stoichiometric oxygen demand, with methane requiring 2 mol O2/mol fuel and hexane requiring 11 mol O2/mol fuel; favoring methane-rich streams reduces ASU energy demand, enhances combustion performance, and lowers separation costs. The combined oxy-combustion cycle attains a thermal efficiency of 33.10% and an exergetic efficiency of 39.98%. Major energy penalties arise from the cryogenic air separation unit and the CCS train, yet operational tuning of CO2 recirculation and steam flow could raise thermal efficiency by up to 2%. The ASU produces oxygen at 96.67% purity with an energy consumption of 0.385 kWh/kg O2, while the CCS achieves 99.99% CO2 capture at 0.41 kWh/kg CO2. Sourcing gas from three production blocks provides flexibility to accommodate supply variability. The modular 272 MW unit demonstrates viability for off-grid power supply, routine flaring reduction, and scalable acid-gas valorization in frontier oilfields. [ABSTRACT FROM AUTHOR]
Database: Energy & Power Source
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An: 193438289
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PubType: Academic Journal
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  Label: Title
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  Data: Decentralized Valorization of Associated Petroleum Gas via Modular Oxy-Combustion and Carbon Capture: A Scalable Strategy for Global Flaring Reduction.
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  Label: Authors
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  Data: <searchLink fieldCode="AR" term="%22Chiriboga%2C+Gonzalo%22">Chiriboga, Gonzalo</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> wgchiriboga@uce.edu.ec</i><br /><searchLink fieldCode="AR" term="%22Núñez%2C+Brandon%22">Núñez, Brandon</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Montero-Calderón%2C+Carolina%22">Montero-Calderón, Carolina</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Gutiérrez%2C+Christian%22">Gutiérrez, Christian</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Almeida%2C+Carlos%22">Almeida, Carlos</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Vega%2C+Michael+A%2E%22">Vega, Michael A.</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Carvajal-Chávez%2C+Ghem%22">Carvajal-Chávez, Ghem</searchLink><relatesTo>1</relatesTo> (AUTHOR)
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  Data: <searchLink fieldCode="JN" term="%22Energies+%2819961073%29%22">Energies (19961073)</searchLink>. Apr2026, Vol. 19 Issue 8, p1949. 24p.
– Name: Subject
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  Data: *<searchLink fieldCode="DE" term="%22Oil+fields%22">Oil fields</searchLink><br />*<searchLink fieldCode="DE" term="%22Flare+gas+systems+%28Chemical+engineering%29%22">Flare gas systems (Chemical engineering)</searchLink><br />*<searchLink fieldCode="DE" term="%22Carbon+sequestration%22">Carbon sequestration</searchLink><br />*<searchLink fieldCode="DE" term="%22Energy+consumption%22">Energy consumption</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: This study evaluates the technical feasibility of deploying containerized oxy-combustion power modules with integrated CO2 capture in remote Ecuadorian Amazon oil fields. Associated petroleum gas is conditioned with a 35 wt.% diethanolamine (DEA) sweetening stage specifically implemented to remove H2S and reduce acid-gas loading prior to combustion, improving fuel quality and protecting downstream equipment while increasing methane mole fraction for combustion. System efficiency is governed by stoichiometric oxygen demand, with methane requiring 2 mol O2/mol fuel and hexane requiring 11 mol O2/mol fuel; favoring methane-rich streams reduces ASU energy demand, enhances combustion performance, and lowers separation costs. The combined oxy-combustion cycle attains a thermal efficiency of 33.10% and an exergetic efficiency of 39.98%. Major energy penalties arise from the cryogenic air separation unit and the CCS train, yet operational tuning of CO2 recirculation and steam flow could raise thermal efficiency by up to 2%. The ASU produces oxygen at 96.67% purity with an energy consumption of 0.385 kWh/kg O2, while the CCS achieves 99.99% CO2 capture at 0.41 kWh/kg CO2. Sourcing gas from three production blocks provides flexibility to accommodate supply variability. The modular 272 MW unit demonstrates viability for off-grid power supply, routine flaring reduction, and scalable acid-gas valorization in frontier oilfields. [ABSTRACT FROM AUTHOR]
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RecordInfo BibRecord:
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        Value: 10.3390/en19081949
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      – Code: eng
        Text: English
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        PageCount: 24
        StartPage: 1949
    Subjects:
      – SubjectFull: Oil fields
        Type: general
      – SubjectFull: Flare gas systems (Chemical engineering)
        Type: general
      – SubjectFull: Carbon sequestration
        Type: general
      – SubjectFull: Energy consumption
        Type: general
    Titles:
      – TitleFull: Decentralized Valorization of Associated Petroleum Gas via Modular Oxy-Combustion and Carbon Capture: A Scalable Strategy for Global Flaring Reduction.
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            NameFull: Chiriboga, Gonzalo
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            NameFull: Núñez, Brandon
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            NameFull: Montero-Calderón, Carolina
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            NameFull: Gutiérrez, Christian
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            NameFull: Almeida, Carlos
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            NameFull: Carvajal-Chávez, Ghem
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            – D: 15
              M: 04
              Text: Apr2026
              Type: published
              Y: 2026
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              Value: 19
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              Value: 8
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            – TitleFull: Energies (19961073)
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