Analysis of potentially toxic elements (PTEs) in lichens using neutron activation analysis (NAA) as a primary method and comparison with a digestion/ICP-MS analysis protocol.

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Title: Analysis of potentially toxic elements (PTEs) in lichens using neutron activation analysis (NAA) as a primary method and comparison with a digestion/ICP-MS analysis protocol.
Authors: Caron, F.1,2 (AUTHOR) fcaron@rmc.ca, Samuleev, P.1 (AUTHOR), Lakanen, M.3,4 (AUTHOR), Anderson, J.3 (AUTHOR), Spiers, G. A.2 (AUTHOR), Beckett, P. J.2 (AUTHOR), Halvorson, B.5 (AUTHOR), Charbonneau, M.5 (AUTHOR)
Source: Journal of Radioanalytical & Nuclear Chemistry. May2026, Vol. 335 Issue 5, p3741-3755. 15p.
Subject Terms: *Lichens, *Nuclear activation analysis, *Inductively coupled plasma mass spectrometry, *Test methods, *Heavy metals, *Trace elements, *Environmental monitoring
Abstract: Lichens are widely used as biomonitors for assessing environmental baselines for stress or recovery of nutrients and potentially toxic elements (PTEs). In this study, lichens were analyzed using neutron activation analysis (NAA) as a primary method, and compared to a digestion-ICP-MS protocol in two independent laboratories. Three fruticose lichens were analyzed: two were collected near Sudbury (Ontario, Canada) and a certified reference material (CRM) lichen (BCR 482). NAA routinely quantified 22 elements in the samples, and generally agreed with the certified and indicative CRM values, except for Co. Inter-methods comparisons had a strong linearity (R2 > 0.93) for all three lichens. A lower slope (0.7257) for one of the lichens (Cladonia spp.) suggested a low digestion recovery relative to NAA. Overall, NAA was a robust primary method for multi-element lichen analysis, especially trace and minor elements, with minimal sample preparation. [ABSTRACT FROM AUTHOR]
Database: Energy & Power Source
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Header DbId: enr
DbLabel: Energy & Power Source
An: 194006673
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
PreciseRelevancyScore: 0
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  Label: Title
  Group: Ti
  Data: Analysis of potentially toxic elements (PTEs) in lichens using neutron activation analysis (NAA) as a primary method and comparison with a digestion/ICP-MS analysis protocol.
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  Data: <searchLink fieldCode="AR" term="%22Caron%2C+F%2E%22">Caron, F.</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<i> fcaron@rmc.ca</i><br /><searchLink fieldCode="AR" term="%22Samuleev%2C+P%2E%22">Samuleev, P.</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Lakanen%2C+M%2E%22">Lakanen, M.</searchLink><relatesTo>3,4</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Anderson%2C+J%2E%22">Anderson, J.</searchLink><relatesTo>3</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Spiers%2C+G%2E+A%2E%22">Spiers, G. A.</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Beckett%2C+P%2E+J%2E%22">Beckett, P. J.</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Halvorson%2C+B%2E%22">Halvorson, B.</searchLink><relatesTo>5</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Charbonneau%2C+M%2E%22">Charbonneau, M.</searchLink><relatesTo>5</relatesTo> (AUTHOR)
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  Data: <searchLink fieldCode="JN" term="%22Journal+of+Radioanalytical+%26+Nuclear+Chemistry%22">Journal of Radioanalytical & Nuclear Chemistry</searchLink>. May2026, Vol. 335 Issue 5, p3741-3755. 15p.
– Name: Subject
  Label: Subject Terms
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  Data: *<searchLink fieldCode="DE" term="%22Lichens%22">Lichens</searchLink><br />*<searchLink fieldCode="DE" term="%22Nuclear+activation+analysis%22">Nuclear activation analysis</searchLink><br />*<searchLink fieldCode="DE" term="%22Inductively+coupled+plasma+mass+spectrometry%22">Inductively coupled plasma mass spectrometry</searchLink><br />*<searchLink fieldCode="DE" term="%22Test+methods%22">Test methods</searchLink><br />*<searchLink fieldCode="DE" term="%22Heavy+metals%22">Heavy metals</searchLink><br />*<searchLink fieldCode="DE" term="%22Trace+elements%22">Trace elements</searchLink><br />*<searchLink fieldCode="DE" term="%22Environmental+monitoring%22">Environmental monitoring</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Lichens are widely used as biomonitors for assessing environmental baselines for stress or recovery of nutrients and potentially toxic elements (PTEs). In this study, lichens were analyzed using neutron activation analysis (NAA) as a primary method, and compared to a digestion-ICP-MS protocol in two independent laboratories. Three fruticose lichens were analyzed: two were collected near Sudbury (Ontario, Canada) and a certified reference material (CRM) lichen (BCR 482). NAA routinely quantified 22 elements in the samples, and generally agreed with the certified and indicative CRM values, except for Co. Inter-methods comparisons had a strong linearity (R2 > 0.93) for all three lichens. A lower slope (0.7257) for one of the lichens (Cladonia spp.) suggested a low digestion recovery relative to NAA. Overall, NAA was a robust primary method for multi-element lichen analysis, especially trace and minor elements, with minimal sample preparation. [ABSTRACT FROM AUTHOR]
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RecordInfo BibRecord:
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        Value: 10.1007/s10967-026-10886-0
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      – Code: eng
        Text: English
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        PageCount: 15
        StartPage: 3741
    Subjects:
      – SubjectFull: Lichens
        Type: general
      – SubjectFull: Nuclear activation analysis
        Type: general
      – SubjectFull: Inductively coupled plasma mass spectrometry
        Type: general
      – SubjectFull: Test methods
        Type: general
      – SubjectFull: Heavy metals
        Type: general
      – SubjectFull: Trace elements
        Type: general
      – SubjectFull: Environmental monitoring
        Type: general
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      – TitleFull: Analysis of potentially toxic elements (PTEs) in lichens using neutron activation analysis (NAA) as a primary method and comparison with a digestion/ICP-MS analysis protocol.
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            NameFull: Caron, F.
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            NameFull: Samuleev, P.
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            – D: 01
              M: 05
              Text: May2026
              Type: published
              Y: 2026
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              Value: 335
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