Convective Heat Transfer Characteristics and Microscopic Mechanisms of Polycarboxylate-Modified 3D Graphene Aqueous Nanofluids in Mini-Channels.

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Title: Convective Heat Transfer Characteristics and Microscopic Mechanisms of Polycarboxylate-Modified 3D Graphene Aqueous Nanofluids in Mini-Channels.
Authors: Liang, Lizhe1 (AUTHOR) lianglizhe@gxu.edu.cn, Li, Qiyuan1 (AUTHOR), Li, Lan1 (AUTHOR)
Source: Energies (19961073). May2026, Vol. 19 Issue 10, p2413. 25p.
Subject Terms: *Graphene, *Nanofluids, *Heat convection, *Thermal conductivity, *Molecular dynamics, *Microchannel flow
Abstract: To overcome graphene aggregation in aqueous nanofluids, polycarboxylate-modified structural graphene (PSG) was synthesized via surface functionalization. Characterizations indicate that the modification preserves the 3D hierarchical porous framework while ensuring exceptional dispersion stability through steric hindrance and enhanced hydrophilicity. Convective heat transfer evaluations demonstrated remarkable enhancement; notably, the 0.1 wt% PSG nanofluid achieved a 46% increase in the heat transfer coefficient over pure water at Re = 4000. Molecular dynamics simulations further revealed the underlying interfacial mechanisms. The surface-anchored oxygen-containing groups induce a dense, hydrogen-bonded hydration layer that restricts local water diffusion. This highly ordered interfacial structure may facilitate vibrational energy exchange across the solid–liquid boundary. Together with the intrinsic high-conductivity 3D skeleton, these microscopic interactions are likely to contribute to the enhanced macroscopic thermal performance, providing a promising framework for designing advanced graphene-based thermal management fluids. [ABSTRACT FROM AUTHOR]
Database: Energy & Power Source
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Header DbId: enr
DbLabel: Energy & Power Source
An: 194141528
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
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Items – Name: Title
  Label: Title
  Group: Ti
  Data: Convective Heat Transfer Characteristics and Microscopic Mechanisms of Polycarboxylate-Modified 3D Graphene Aqueous Nanofluids in Mini-Channels.
– Name: Author
  Label: Authors
  Group: Au
  Data: <searchLink fieldCode="AR" term="%22Liang%2C+Lizhe%22">Liang, Lizhe</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> lianglizhe@gxu.edu.cn</i><br /><searchLink fieldCode="AR" term="%22Li%2C+Qiyuan%22">Li, Qiyuan</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Li%2C+Lan%22">Li, Lan</searchLink><relatesTo>1</relatesTo> (AUTHOR)
– Name: TitleSource
  Label: Source
  Group: Src
  Data: <searchLink fieldCode="JN" term="%22Energies+%2819961073%29%22">Energies (19961073)</searchLink>. May2026, Vol. 19 Issue 10, p2413. 25p.
– Name: Subject
  Label: Subject Terms
  Group: Su
  Data: *<searchLink fieldCode="DE" term="%22Graphene%22">Graphene</searchLink><br />*<searchLink fieldCode="DE" term="%22Nanofluids%22">Nanofluids</searchLink><br />*<searchLink fieldCode="DE" term="%22Heat+convection%22">Heat convection</searchLink><br />*<searchLink fieldCode="DE" term="%22Thermal+conductivity%22">Thermal conductivity</searchLink><br />*<searchLink fieldCode="DE" term="%22Molecular+dynamics%22">Molecular dynamics</searchLink><br />*<searchLink fieldCode="DE" term="%22Microchannel+flow%22">Microchannel flow</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: To overcome graphene aggregation in aqueous nanofluids, polycarboxylate-modified structural graphene (PSG) was synthesized via surface functionalization. Characterizations indicate that the modification preserves the 3D hierarchical porous framework while ensuring exceptional dispersion stability through steric hindrance and enhanced hydrophilicity. Convective heat transfer evaluations demonstrated remarkable enhancement; notably, the 0.1 wt% PSG nanofluid achieved a 46% increase in the heat transfer coefficient over pure water at Re = 4000. Molecular dynamics simulations further revealed the underlying interfacial mechanisms. The surface-anchored oxygen-containing groups induce a dense, hydrogen-bonded hydration layer that restricts local water diffusion. This highly ordered interfacial structure may facilitate vibrational energy exchange across the solid–liquid boundary. Together with the intrinsic high-conductivity 3D skeleton, these microscopic interactions are likely to contribute to the enhanced macroscopic thermal performance, providing a promising framework for designing advanced graphene-based thermal management fluids. [ABSTRACT FROM AUTHOR]
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RecordInfo BibRecord:
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    Identifiers:
      – Type: doi
        Value: 10.3390/en19102413
    Languages:
      – Code: eng
        Text: English
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        PageCount: 25
        StartPage: 2413
    Subjects:
      – SubjectFull: Graphene
        Type: general
      – SubjectFull: Nanofluids
        Type: general
      – SubjectFull: Heat convection
        Type: general
      – SubjectFull: Thermal conductivity
        Type: general
      – SubjectFull: Molecular dynamics
        Type: general
      – SubjectFull: Microchannel flow
        Type: general
    Titles:
      – TitleFull: Convective Heat Transfer Characteristics and Microscopic Mechanisms of Polycarboxylate-Modified 3D Graphene Aqueous Nanofluids in Mini-Channels.
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            NameFull: Liang, Lizhe
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            NameFull: Li, Qiyuan
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            – D: 15
              M: 05
              Text: May2026
              Type: published
              Y: 2026
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              Value: 19
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              Value: 10
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            – TitleFull: Energies (19961073)
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