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Critical Aspects of Heme-Peroxo-Cu Complex Structure and Nature of Proton Source Dictate Metal-O(peroxo) Breakage versus Reductive O-O Cleavage Chemistry.

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Title: Critical Aspects of Heme-Peroxo-Cu Complex Structure and Nature of Proton Source Dictate Metal-O(peroxo) Breakage versus Reductive O-O Cleavage Chemistry.
Authors: Adam SM; Johns Hopkins University , Baltimore, Maryland 21218, United States., Garcia-Bosch I; Johns Hopkins University , Baltimore, Maryland 21218, United States., Schaefer AW; Department of Chemistry, Stanford University , Stanford, California 94305, United States., Sharma SK; Johns Hopkins University , Baltimore, Maryland 21218, United States., Siegler MA; Johns Hopkins University , Baltimore, Maryland 21218, United States., Solomon EI; Department of Chemistry, Stanford University , Stanford, California 94305, United States., Karlin KD; Johns Hopkins University , Baltimore, Maryland 21218, United States.
Source: Journal of the American Chemical Society [J Am Chem Soc] 2017 Jan 11; Vol. 139 (1), pp. 472-481. Date of Electronic Publication: 2016 Dec 28.
Publication Type: Journal Article; Research Support, N.I.H., Extramural; Research Support, Non-U.S. Gov't
Journal Info: Publisher: American Chemical Society Country of Publication: United States NLM ID: 7503056 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1520-5126 (Electronic) Linking ISSN: 00027863 NLM ISO Abbreviation: J Am Chem Soc Subsets: MEDLINE
Database: MEDLINE Ultimate
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PubType: Academic Journal
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        Value: 10.1021/jacs.6b11322
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