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Reactivity of syn-CH3CHOO with H2O enhanced through a roaming mechanism in the entrance channel.

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Title: Reactivity of syn-CH3CHOO with H2O enhanced through a roaming mechanism in the entrance channel.
Authors: Liu Y; State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, China.; School of Materials Science and Engineering, Anyang Institute of Technology, Anyang, China., Liu L; State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, China.; Department of Chemical Physics, University of Science and Technology of China, Hefei, China., Fu Y; State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, China., Jiang H; State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, China.; Department of Chemical Physics, University of Science and Technology of China, Hefei, China., Wu H; State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, China., Liu Y; State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, China.; Department of Chemical Physics, University of Science and Technology of China, Hefei, China., Lu X; State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, China., Zhou X; State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, China., Li H; State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, China.; University of Chinese Academy of Sciences, Beijing, China., Skodje RT; Department of Chemistry, University of Colorado, Boulder, CO, USA., Wang X; Department of Chemical Physics, University of Science and Technology of China, Hefei, China.; Hefei National Laboratory, Hefei, China., Fu B; State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, China. bina@dicp.ac.cn.; University of Chinese Academy of Sciences, Beijing, China. bina@dicp.ac.cn.; Hefei National Laboratory, Hefei, China. bina@dicp.ac.cn., Dong W; State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, China. wrdong@dicp.ac.cn.; University of Chinese Academy of Sciences, Beijing, China. wrdong@dicp.ac.cn.; Hefei National Laboratory, Hefei, China. wrdong@dicp.ac.cn., Zhang DH; State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, China. zhangdh@dicp.ac.cn.; University of Chinese Academy of Sciences, Beijing, China. zhangdh@dicp.ac.cn.; Hefei National Laboratory, Hefei, China. zhangdh@dicp.ac.cn., Yang X; State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, China. xmyang@dicp.ac.cn.; Hefei National Laboratory, Hefei, China. xmyang@dicp.ac.cn.; Department of Chemistry and Center for Advanced Light Source Research, College of Science, Southern University of Science and Technology, Shenzhen, China. xmyang@dicp.ac.cn.
Source: Nature chemistry [Nat Chem] 2025 Jun; Vol. 17 (6), pp. 897-903. Date of Electronic Publication: 2025 Apr 16.
Publication Type: Journal Article
Journal Info: Publisher: Nature Pub. Group Country of Publication: England NLM ID: 101499734 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1755-4349 (Electronic) Linking ISSN: 17554330 NLM ISO Abbreviation: Nat Chem Subsets: MEDLINE; PubMed not MEDLINE
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  Data: <searchLink fieldCode="AU" term="%22Liu+Y%22">Liu Y</searchLink>; State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, China.; School of Materials Science and Engineering, Anyang Institute of Technology, Anyang, China.<br /><searchLink fieldCode="AU" term="%22Liu+L%22">Liu L</searchLink>; State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, China.; Department of Chemical Physics, University of Science and Technology of China, Hefei, China.<br /><searchLink fieldCode="AU" term="%22Fu+Y%22">Fu Y</searchLink>; State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, China.<br /><searchLink fieldCode="AU" term="%22Jiang+H%22">Jiang H</searchLink>; State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, China.; Department of Chemical Physics, University of Science and Technology of China, Hefei, China.<br /><searchLink fieldCode="AU" term="%22Wu+H%22">Wu H</searchLink>; State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, China.<br /><searchLink fieldCode="AU" term="%22Liu+Y%22">Liu Y</searchLink>; State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, China.; Department of Chemical Physics, University of Science and Technology of China, Hefei, China.<br /><searchLink fieldCode="AU" term="%22Lu+X%22">Lu X</searchLink>; State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, China.<br /><searchLink fieldCode="AU" term="%22Zhou+X%22">Zhou X</searchLink>; State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, China.<br /><searchLink fieldCode="AU" term="%22Li+H%22">Li H</searchLink>; State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, China.; University of Chinese Academy of Sciences, Beijing, China.<br /><searchLink fieldCode="AU" term="%22Skodje+RT%22">Skodje RT</searchLink>; Department of Chemistry, University of Colorado, Boulder, CO, USA.<br /><searchLink fieldCode="AU" term="%22Wang+X%22">Wang X</searchLink>; Department of Chemical Physics, University of Science and Technology of China, Hefei, China.; Hefei National Laboratory, Hefei, China.<br /><searchLink fieldCode="AU" term="%22Fu+B%22">Fu B</searchLink>; State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, China. bina@dicp.ac.cn.; University of Chinese Academy of Sciences, Beijing, China. bina@dicp.ac.cn.; Hefei National Laboratory, Hefei, China. bina@dicp.ac.cn.<br /><searchLink fieldCode="AU" term="%22Dong+W%22">Dong W</searchLink>; State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, China. wrdong@dicp.ac.cn.; University of Chinese Academy of Sciences, Beijing, China. wrdong@dicp.ac.cn.; Hefei National Laboratory, Hefei, China. wrdong@dicp.ac.cn.<br /><searchLink fieldCode="AU" term="%22Zhang+DH%22">Zhang DH</searchLink>; State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, China. zhangdh@dicp.ac.cn.; University of Chinese Academy of Sciences, Beijing, China. zhangdh@dicp.ac.cn.; Hefei National Laboratory, Hefei, China. zhangdh@dicp.ac.cn.<br /><searchLink fieldCode="AU" term="%22Yang+X%22">Yang X</searchLink>; State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, China. xmyang@dicp.ac.cn.; Hefei National Laboratory, Hefei, China. xmyang@dicp.ac.cn.; Department of Chemistry and Center for Advanced Light Source Research, College of Science, Southern University of Science and Technology, Shenzhen, China. xmyang@dicp.ac.cn.
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        Value: 10.1038/s41557-025-01798-9
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