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What lies beyond thioredoxin reductase? Cyclometallated gold compounds reveal Sec selectivity in glutathione peroxidases.

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Title: What lies beyond thioredoxin reductase? Cyclometallated gold compounds reveal Sec selectivity in glutathione peroxidases.
Authors: Kanavos I; Université de Pau et des Pays de l'Adour, E2S UPPA, CNRS, IPREM UMR 5254, 2 Av. du Presidnet Pierre Angotcedex 09, 64053, Pau, France., Nakahata DH; Donostia International Physics Center - DIPC, Paseo de Manuel Lardizabal 4, Euskadi, 20018, Donostia, Gipuzkoa, Spain., Barrett MS; Division of Biochemistry, Department of Medical Biochemistry and Biophysics, Karolinska Institutet, SE, 171 77, Stockholm, Sweden; Early Translation Branch, National Center for Advancing Translational Sciences, National Institute of Health, 9800 Medical Center Drive, Rockville, MD, 20850, United States., Dos Santos AF; Rudolf Virchow Center for Integrative and Translational Bioimaging, University of Würzburg, Würzburg, Germany., Zubiria-Ulacia M; Donostia International Physics Center - DIPC, Paseo de Manuel Lardizabal 4, Euskadi, 20018, Donostia, Gipuzkoa, Spain; Polimero eta Material Aurreratuak: Fisika, Kimika eta Teknologia, Kimika Fakultatea, Euskal Herriko Unibertsitatea UPV/EHU, Paseo Manuel de Lardizabal 3, Euskadi, 20018, Donostia, Gipuzkoa, Spain., Pieslinger GE; Donostia International Physics Center - DIPC, Paseo de Manuel Lardizabal 4, Euskadi, 20018, Donostia, Gipuzkoa, Spain; CONICET-Universidad de Buenos Aires, Instituto de Química y Fisicoquímica Biológicas (IQUIFIB), Buenos Aires, C1113AAD, Argentina., da Silva Teixeira AB; Rudolf Virchow Center for Integrative and Translational Bioimaging, University of Würzburg, Würzburg, Germany; Universidade Federal de São Paulo (UNIFESP), Departamento de Oncologia Clínica e Experimental, São Paulo, 04037-003, Brazil., Medeiros I; Rudolf Virchow Center for Integrative and Translational Bioimaging, University of Würzburg, Würzburg, Germany; Departamento de Bioquímica, Instituto de Química (IQUSP), Universidade de São Paulo, São Paulo, 05508-000, Brazil., Rocha CRR; Rudolf Virchow Center for Integrative and Translational Bioimaging, University of Würzburg, Würzburg, Germany; Universidade Federal de São Paulo (UNIFESP), Departamento de Oncologia Clínica e Experimental, São Paulo, 04037-003, Brazil., Eberle J; Rudolf Virchow Center for Integrative and Translational Bioimaging, University of Würzburg, Würzburg, Germany., Lobinski R; Université de Pau et des Pays de l'Adour, E2S UPPA, CNRS, IPREM UMR 5254, 2 Av. du Presidnet Pierre Angotcedex 09, 64053, Pau, France; Chair of Analytical Chemistry, Warsaw University of Technology, 00-664, Warsaw, Poland., Matxain JM; Donostia International Physics Center - DIPC, Paseo de Manuel Lardizabal 4, Euskadi, 20018, Donostia, Gipuzkoa, Spain; Polimero eta Material Aurreratuak: Fisika, Kimika eta Teknologia, Kimika Fakultatea, Euskal Herriko Unibertsitatea UPV/EHU, Paseo Manuel de Lardizabal 3, Euskadi, 20018, Donostia, Gipuzkoa, Spain., Hall MD; Early Translation Branch, National Center for Advancing Translational Sciences, National Institute of Health, 9800 Medical Center Drive, Rockville, MD, 20850, United States., Friedmann Angeli JP; Rudolf Virchow Center for Integrative and Translational Bioimaging, University of Würzburg, Würzburg, Germany., Arnér ESJ; Division of Biochemistry, Department of Medical Biochemistry and Biophysics, Karolinska Institutet, SE, 171 77, Stockholm, Sweden; Department of Selenoprotein Research and the National Tumor Biology Laboratory, National Institute of Oncology, 1122, Budapest, Hungary., Ronga L; Université de Pau et des Pays de l'Adour, E2S UPPA, CNRS, IPREM UMR 5254, 2 Av. du Presidnet Pierre Angotcedex 09, 64053, Pau, France. Electronic address: luisa.ronga@univ-pau.fr., de Paiva REF; Donostia International Physics Center - DIPC, Paseo de Manuel Lardizabal 4, Euskadi, 20018, Donostia, Gipuzkoa, Spain. Electronic address: raphael.depaiva@dipc.org.
Source: Free radical biology & medicine [Free Radic Biol Med] 2026 Apr; Vol. 247, pp. 139-156. Date of Electronic Publication: 2026 Feb 05.
Publication Type: Journal Article
Journal Info: Publisher: Elsevier Science Country of Publication: United States NLM ID: 8709159 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1873-4596 (Electronic) Linking ISSN: 08915849 NLM ISO Abbreviation: Free Radic Biol Med Subsets: MEDLINE
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  Data: What lies beyond thioredoxin reductase? Cyclometallated gold compounds reveal Sec selectivity in glutathione peroxidases.
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  Data: <searchLink fieldCode="AU" term="%22Kanavos+I%22">Kanavos I</searchLink>; Université de Pau et des Pays de l'Adour, E2S UPPA, CNRS, IPREM UMR 5254, 2 Av. du Presidnet Pierre Angotcedex 09, 64053, Pau, France.<br /><searchLink fieldCode="AU" term="%22Nakahata+DH%22">Nakahata DH</searchLink>; Donostia International Physics Center - DIPC, Paseo de Manuel Lardizabal 4, Euskadi, 20018, Donostia, Gipuzkoa, Spain.<br /><searchLink fieldCode="AU" term="%22Barrett+MS%22">Barrett MS</searchLink>; Division of Biochemistry, Department of Medical Biochemistry and Biophysics, Karolinska Institutet, SE, 171 77, Stockholm, Sweden; Early Translation Branch, National Center for Advancing Translational Sciences, National Institute of Health, 9800 Medical Center Drive, Rockville, MD, 20850, United States.<br /><searchLink fieldCode="AU" term="%22Dos+Santos+AF%22">Dos Santos AF</searchLink>; Rudolf Virchow Center for Integrative and Translational Bioimaging, University of Würzburg, Würzburg, Germany.<br /><searchLink fieldCode="AU" term="%22Zubiria-Ulacia+M%22">Zubiria-Ulacia M</searchLink>; Donostia International Physics Center - DIPC, Paseo de Manuel Lardizabal 4, Euskadi, 20018, Donostia, Gipuzkoa, Spain; Polimero eta Material Aurreratuak: Fisika, Kimika eta Teknologia, Kimika Fakultatea, Euskal Herriko Unibertsitatea UPV/EHU, Paseo Manuel de Lardizabal 3, Euskadi, 20018, Donostia, Gipuzkoa, Spain.<br /><searchLink fieldCode="AU" term="%22Pieslinger+GE%22">Pieslinger GE</searchLink>; Donostia International Physics Center - DIPC, Paseo de Manuel Lardizabal 4, Euskadi, 20018, Donostia, Gipuzkoa, Spain; CONICET-Universidad de Buenos Aires, Instituto de Química y Fisicoquímica Biológicas (IQUIFIB), Buenos Aires, C1113AAD, Argentina.<br /><searchLink fieldCode="AU" term="%22da+Silva+Teixeira+AB%22">da Silva Teixeira AB</searchLink>; Rudolf Virchow Center for Integrative and Translational Bioimaging, University of Würzburg, Würzburg, Germany; Universidade Federal de São Paulo (UNIFESP), Departamento de Oncologia Clínica e Experimental, São Paulo, 04037-003, Brazil.<br /><searchLink fieldCode="AU" term="%22Medeiros+I%22">Medeiros I</searchLink>; Rudolf Virchow Center for Integrative and Translational Bioimaging, University of Würzburg, Würzburg, Germany; Departamento de Bioquímica, Instituto de Química (IQUSP), Universidade de São Paulo, São Paulo, 05508-000, Brazil.<br /><searchLink fieldCode="AU" term="%22Rocha+CRR%22">Rocha CRR</searchLink>; Rudolf Virchow Center for Integrative and Translational Bioimaging, University of Würzburg, Würzburg, Germany; Universidade Federal de São Paulo (UNIFESP), Departamento de Oncologia Clínica e Experimental, São Paulo, 04037-003, Brazil.<br /><searchLink fieldCode="AU" term="%22Eberle+J%22">Eberle J</searchLink>; Rudolf Virchow Center for Integrative and Translational Bioimaging, University of Würzburg, Würzburg, Germany.<br /><searchLink fieldCode="AU" term="%22Lobinski+R%22">Lobinski R</searchLink>; Université de Pau et des Pays de l'Adour, E2S UPPA, CNRS, IPREM UMR 5254, 2 Av. du Presidnet Pierre Angotcedex 09, 64053, Pau, France; Chair of Analytical Chemistry, Warsaw University of Technology, 00-664, Warsaw, Poland.<br /><searchLink fieldCode="AU" term="%22Matxain+JM%22">Matxain JM</searchLink>; Donostia International Physics Center - DIPC, Paseo de Manuel Lardizabal 4, Euskadi, 20018, Donostia, Gipuzkoa, Spain; Polimero eta Material Aurreratuak: Fisika, Kimika eta Teknologia, Kimika Fakultatea, Euskal Herriko Unibertsitatea UPV/EHU, Paseo Manuel de Lardizabal 3, Euskadi, 20018, Donostia, Gipuzkoa, Spain.<br /><searchLink fieldCode="AU" term="%22Hall+MD%22">Hall MD</searchLink>; Early Translation Branch, National Center for Advancing Translational Sciences, National Institute of Health, 9800 Medical Center Drive, Rockville, MD, 20850, United States.<br /><searchLink fieldCode="AU" term="%22Friedmann+Angeli+JP%22">Friedmann Angeli JP</searchLink>; Rudolf Virchow Center for Integrative and Translational Bioimaging, University of Würzburg, Würzburg, Germany.<br /><searchLink fieldCode="AU" term="%22Arnér+ESJ%22">Arnér ESJ</searchLink>; Division of Biochemistry, Department of Medical Biochemistry and Biophysics, Karolinska Institutet, SE, 171 77, Stockholm, Sweden; Department of Selenoprotein Research and the National Tumor Biology Laboratory, National Institute of Oncology, 1122, Budapest, Hungary.<br /><searchLink fieldCode="AU" term="%22Ronga+L%22">Ronga L</searchLink>; Université de Pau et des Pays de l'Adour, E2S UPPA, CNRS, IPREM UMR 5254, 2 Av. du Presidnet Pierre Angotcedex 09, 64053, Pau, France. Electronic address: luisa.ronga@univ-pau.fr.<br /><searchLink fieldCode="AU" term="%22de+Paiva+REF%22">de Paiva REF</searchLink>; Donostia International Physics Center - DIPC, Paseo de Manuel Lardizabal 4, Euskadi, 20018, Donostia, Gipuzkoa, Spain. Electronic address: raphael.depaiva@dipc.org.
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  Data: <searchLink fieldCode="JN" term="%228709159%22">Free radical biology & medicine</searchLink> [Free Radic Biol Med] 2026 Apr; Vol. 247, pp. 139-156. <i>Date of Electronic Publication: </i>2026 Feb 05.
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