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Beyond Passive Substituents: Tosyl-Directed Self-Templation Enables Selective Pillar[4 + 1]arene Formation and Topology Switching.

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Title: Beyond Passive Substituents: Tosyl-Directed Self-Templation Enables Selective Pillar[4 + 1]arene Formation and Topology Switching.
Authors: Ruengsuk A; Department of Chemistry and Center of Excellence for Innovation in Chemistry (PERCH-CIC), Faculty of Science, Mahidol University, 272 Rama VI Road, Thung Phaya Thai, Ratchathewi, Bangkok 10400, Thailand., Khamphaijun K; Department of Chemistry and Center of Excellence for Innovation in Chemistry (PERCH-CIC), Faculty of Science, Mahidol University, 272 Rama VI Road, Thung Phaya Thai, Ratchathewi, Bangkok 10400, Thailand., Laoviwat P; Department of Chemistry and Center of Excellence for Innovation in Chemistry (PERCH-CIC), Faculty of Science, Mahidol University, 272 Rama VI Road, Thung Phaya Thai, Ratchathewi, Bangkok 10400, Thailand., Kamonsutthipaijit N; Synchrotron Light Research Institute, Nakhon Ratchasima 30000, Thailand., Tuntirungrotechai J; Department of Chemistry and Center of Excellence for Innovation in Chemistry (PERCH-CIC), Faculty of Science, Mahidol University, 272 Rama VI Road, Thung Phaya Thai, Ratchathewi, Bangkok 10400, Thailand., Shigeta Y; Center for Computational Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8577, Japan., Hengphasatporn K; Center for Computational Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8577, Japan., Harding DJ; School of Chemistry, Institute of Science, Suranaree University of Technology, Nakhon Ratchasima 30000, Thailand., Bunchuay T; Department of Chemistry and Center of Excellence for Innovation in Chemistry (PERCH-CIC), Faculty of Science, Mahidol University, 272 Rama VI Road, Thung Phaya Thai, Ratchathewi, Bangkok 10400, Thailand.; Center of Sustainable Energy and Green Materials, Mahidol University, Salaya, Nakhon Pathom 73170, Thailand.
Source: Journal of the American Chemical Society [J Am Chem Soc] 2026 Jun 17; Vol. 148 (23), pp. 23965-23975. Date of Electronic Publication: 2026 May 27.
Publication Type: Journal Article
Journal Info: Publisher: American Chemical Society Country of Publication: United States NLM ID: 7503056 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1520-5126 (Electronic) Linking ISSN: 00027863 NLM ISO Abbreviation: J Am Chem Soc Subsets: MEDLINE; PubMed not MEDLINE
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  Data: <searchLink fieldCode="AU" term="%22Ruengsuk+A%22">Ruengsuk A</searchLink>; Department of Chemistry and Center of Excellence for Innovation in Chemistry (PERCH-CIC), Faculty of Science, Mahidol University, 272 Rama VI Road, Thung Phaya Thai, Ratchathewi, Bangkok 10400, Thailand.<br /><searchLink fieldCode="AU" term="%22Khamphaijun+K%22">Khamphaijun K</searchLink>; Department of Chemistry and Center of Excellence for Innovation in Chemistry (PERCH-CIC), Faculty of Science, Mahidol University, 272 Rama VI Road, Thung Phaya Thai, Ratchathewi, Bangkok 10400, Thailand.<br /><searchLink fieldCode="AU" term="%22Laoviwat+P%22">Laoviwat P</searchLink>; Department of Chemistry and Center of Excellence for Innovation in Chemistry (PERCH-CIC), Faculty of Science, Mahidol University, 272 Rama VI Road, Thung Phaya Thai, Ratchathewi, Bangkok 10400, Thailand.<br /><searchLink fieldCode="AU" term="%22Kamonsutthipaijit+N%22">Kamonsutthipaijit N</searchLink>; Synchrotron Light Research Institute, Nakhon Ratchasima 30000, Thailand.<br /><searchLink fieldCode="AU" term="%22Tuntirungrotechai+J%22">Tuntirungrotechai J</searchLink>; Department of Chemistry and Center of Excellence for Innovation in Chemistry (PERCH-CIC), Faculty of Science, Mahidol University, 272 Rama VI Road, Thung Phaya Thai, Ratchathewi, Bangkok 10400, Thailand.<br /><searchLink fieldCode="AU" term="%22Shigeta+Y%22">Shigeta Y</searchLink>; Center for Computational Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8577, Japan.<br /><searchLink fieldCode="AU" term="%22Hengphasatporn+K%22">Hengphasatporn K</searchLink>; Center for Computational Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8577, Japan.<br /><searchLink fieldCode="AU" term="%22Harding+DJ%22">Harding DJ</searchLink>; School of Chemistry, Institute of Science, Suranaree University of Technology, Nakhon Ratchasima 30000, Thailand.<br /><searchLink fieldCode="AU" term="%22Bunchuay+T%22">Bunchuay T</searchLink>; Department of Chemistry and Center of Excellence for Innovation in Chemistry (PERCH-CIC), Faculty of Science, Mahidol University, 272 Rama VI Road, Thung Phaya Thai, Ratchathewi, Bangkok 10400, Thailand.; Center of Sustainable Energy and Green Materials, Mahidol University, Salaya, Nakhon Pathom 73170, Thailand.
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  Data: <searchLink fieldCode="JN" term="%227503056%22">Journal of the American Chemical Society</searchLink> [J Am Chem Soc] 2026 Jun 17; Vol. 148 (23), pp. 23965-23975. <i>Date of Electronic Publication: </i>2026 May 27.
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              Text: 2026 Jun 17
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