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Biocatalytic C3 β-O-Glycosylation of Triterpenes and Sterols to Synthesize Natural and Unnatural Saponins.

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Title: Biocatalytic C3 β-O-Glycosylation of Triterpenes and Sterols to Synthesize Natural and Unnatural Saponins.
Authors: Winegar PH; California Institute for Quantitative Biosciences (QB3 Institute), University of California, Berkeley, Berkeley, California 94720, United States.; Biological Systems and Engineering Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States.; Joint BioEnergy Institute, Lawrence Berkeley National Laboratory, Emeryville, California 94608, United States., Hudson GA; California Institute for Quantitative Biosciences (QB3 Institute), University of California, Berkeley, Berkeley, California 94720, United States.; Biological Systems and Engineering Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States.; Joint BioEnergy Institute, Lawrence Berkeley National Laboratory, Emeryville, California 94608, United States., Benedict RP; Biological Systems and Engineering Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States.; Joint BioEnergy Institute, Lawrence Berkeley National Laboratory, Emeryville, California 94608, United States.; Department of Chemistry, University of California, Berkeley, Berkeley, California 94720, United States., Sy CZ; Biological Systems and Engineering Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States.; Joint BioEnergy Institute, Lawrence Berkeley National Laboratory, Emeryville, California 94608, United States.; Department of Chemical & Biomolecular Engineering, University of California, Berkeley, Berkeley, California 94720, United States., Han TY; Biological Systems and Engineering Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States.; Joint BioEnergy Institute, Lawrence Berkeley National Laboratory, Emeryville, California 94608, United States.; Department of Bioengineering, University of California, Berkeley, Berkeley, California 94720, United States.; Management, Entrepreneurship & Technology Program, University of California, Berkeley, Berkeley, California 94720, United States., FitzGerald DM; Biological Systems and Engineering Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States.; Joint BioEnergy Institute, Lawrence Berkeley National Laboratory, Emeryville, California 94608, United States.; Department of Molecular & Cell Biology, University of California, Berkeley, Berkeley, California 94720, United States., Mahajan RS; Biological Systems and Engineering Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States.; Joint BioEnergy Institute, Lawrence Berkeley National Laboratory, Emeryville, California 94608, United States.; Department of Chemical & Biomolecular Engineering, University of California, Berkeley, Berkeley, California 94720, United States., Gravel PJ; Biological Systems and Engineering Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States.; Joint BioEnergy Institute, Lawrence Berkeley National Laboratory, Emeryville, California 94608, United States.; Department of Chemistry, University of California, Berkeley, Berkeley, California 94720, United States.; Department of Chemical & Biomolecular Engineering, University of California, Berkeley, Berkeley, California 94720, United States., Roberts JB; Biological Systems and Engineering Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States.; Joint BioEnergy Institute, Lawrence Berkeley National Laboratory, Emeryville, California 94608, United States.; Department of Bioengineering, University of California, Berkeley, Berkeley, California 94720, United States., Lanclos N; Biological Systems and Engineering Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States.; Joint BioEnergy Institute, Lawrence Berkeley National Laboratory, Emeryville, California 94608, United States.; Department of Bioengineering, University of California, Berkeley, Berkeley, California 94720, United States., Huang M; Biological Systems and Engineering Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States.; Joint BioEnergy Institute, Lawrence Berkeley National Laboratory, Emeryville, California 94608, United States.; Department of Bioengineering, University of California, Berkeley, Berkeley, California 94720, United States., Iavarone AT; California Institute for Quantitative Biosciences (QB3 Institute), University of California, Berkeley, Berkeley, California 94720, United States., Keasling JD; California Institute for Quantitative Biosciences (QB3 Institute), University of California, Berkeley, Berkeley, California 94720, United States.; Biological Systems and Engineering Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States.; Joint BioEnergy Institute, Lawrence Berkeley National Laboratory, Emeryville, California 94608, United States.; Department of Chemical & Biomolecular Engineering, University of California, Berkeley, Berkeley, California 94720, United States.; Department of Bioengineering, University of California, Berkeley, Berkeley, California 94720, United States.; The Novo Nordisk Foundation Center for Biosustainability, Technical University of Denmark, Kemitorvet, Building 220, Kongens Lyngby 2800, Denmark.
Source: Journal of the American Chemical Society [J Am Chem Soc] 2026 Jul 15; Vol. 148 (27), pp. 29124-29137. Date of Electronic Publication: 2026 Jul 02.
Publication Type: Journal Article
Journal Info: Publisher: American Chemical Society Country of Publication: United States NLM ID: 7503056 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1520-5126 (Electronic) Linking ISSN: 00027863 NLM ISO Abbreviation: J Am Chem Soc Subsets: MEDLINE
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  Data: Biocatalytic C3 β-O-Glycosylation of Triterpenes and Sterols to Synthesize Natural and Unnatural Saponins.
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  Data: <searchLink fieldCode="AU" term="%22Winegar+PH%22">Winegar PH</searchLink>; California Institute for Quantitative Biosciences (QB3 Institute), University of California, Berkeley, Berkeley, California 94720, United States.; Biological Systems and Engineering Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States.; Joint BioEnergy Institute, Lawrence Berkeley National Laboratory, Emeryville, California 94608, United States.<br /><searchLink fieldCode="AU" term="%22Hudson+GA%22">Hudson GA</searchLink>; California Institute for Quantitative Biosciences (QB3 Institute), University of California, Berkeley, Berkeley, California 94720, United States.; Biological Systems and Engineering Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States.; Joint BioEnergy Institute, Lawrence Berkeley National Laboratory, Emeryville, California 94608, United States.<br /><searchLink fieldCode="AU" term="%22Benedict+RP%22">Benedict RP</searchLink>; Biological Systems and Engineering Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States.; Joint BioEnergy Institute, Lawrence Berkeley National Laboratory, Emeryville, California 94608, United States.; Department of Chemistry, University of California, Berkeley, Berkeley, California 94720, United States.<br /><searchLink fieldCode="AU" term="%22Sy+CZ%22">Sy CZ</searchLink>; Biological Systems and Engineering Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States.; Joint BioEnergy Institute, Lawrence Berkeley National Laboratory, Emeryville, California 94608, United States.; Department of Chemical & Biomolecular Engineering, University of California, Berkeley, Berkeley, California 94720, United States.<br /><searchLink fieldCode="AU" term="%22Han+TY%22">Han TY</searchLink>; Biological Systems and Engineering Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States.; Joint BioEnergy Institute, Lawrence Berkeley National Laboratory, Emeryville, California 94608, United States.; Department of Bioengineering, University of California, Berkeley, Berkeley, California 94720, United States.; Management, Entrepreneurship & Technology Program, University of California, Berkeley, Berkeley, California 94720, United States.<br /><searchLink fieldCode="AU" term="%22FitzGerald+DM%22">FitzGerald DM</searchLink>; Biological Systems and Engineering Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States.; Joint BioEnergy Institute, Lawrence Berkeley National Laboratory, Emeryville, California 94608, United States.; Department of Molecular & Cell Biology, University of California, Berkeley, Berkeley, California 94720, United States.<br /><searchLink fieldCode="AU" term="%22Mahajan+RS%22">Mahajan RS</searchLink>; Biological Systems and Engineering Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States.; Joint BioEnergy Institute, Lawrence Berkeley National Laboratory, Emeryville, California 94608, United States.; Department of Chemical & Biomolecular Engineering, University of California, Berkeley, Berkeley, California 94720, United States.<br /><searchLink fieldCode="AU" term="%22Gravel+PJ%22">Gravel PJ</searchLink>; Biological Systems and Engineering Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States.; Joint BioEnergy Institute, Lawrence Berkeley National Laboratory, Emeryville, California 94608, United States.; Department of Chemistry, University of California, Berkeley, Berkeley, California 94720, United States.; Department of Chemical & Biomolecular Engineering, University of California, Berkeley, Berkeley, California 94720, United States.<br /><searchLink fieldCode="AU" term="%22Roberts+JB%22">Roberts JB</searchLink>; Biological Systems and Engineering Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States.; Joint BioEnergy Institute, Lawrence Berkeley National Laboratory, Emeryville, California 94608, United States.; Department of Bioengineering, University of California, Berkeley, Berkeley, California 94720, United States.<br /><searchLink fieldCode="AU" term="%22Lanclos+N%22">Lanclos N</searchLink>; Biological Systems and Engineering Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States.; Joint BioEnergy Institute, Lawrence Berkeley National Laboratory, Emeryville, California 94608, United States.; Department of Bioengineering, University of California, Berkeley, Berkeley, California 94720, United States.<br /><searchLink fieldCode="AU" term="%22Huang+M%22">Huang M</searchLink>; Biological Systems and Engineering Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States.; Joint BioEnergy Institute, Lawrence Berkeley National Laboratory, Emeryville, California 94608, United States.; Department of Bioengineering, University of California, Berkeley, Berkeley, California 94720, United States.<br /><searchLink fieldCode="AU" term="%22Iavarone+AT%22">Iavarone AT</searchLink>; California Institute for Quantitative Biosciences (QB3 Institute), University of California, Berkeley, Berkeley, California 94720, United States.<br /><searchLink fieldCode="AU" term="%22Keasling+JD%22">Keasling JD</searchLink>; California Institute for Quantitative Biosciences (QB3 Institute), University of California, Berkeley, Berkeley, California 94720, United States.; Biological Systems and Engineering Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States.; Joint BioEnergy Institute, Lawrence Berkeley National Laboratory, Emeryville, California 94608, United States.; Department of Chemical & Biomolecular Engineering, University of California, Berkeley, Berkeley, California 94720, United States.; Department of Bioengineering, University of California, Berkeley, Berkeley, California 94720, United States.; The Novo Nordisk Foundation Center for Biosustainability, Technical University of Denmark, Kemitorvet, Building 220, Kongens Lyngby 2800, Denmark.
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  Data: <searchLink fieldCode="JN" term="%227503056%22">Journal of the American Chemical Society</searchLink> [J Am Chem Soc] 2026 Jul 15; Vol. 148 (27), pp. 29124-29137. <i>Date of Electronic Publication: </i>2026 Jul 02.
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        Value: 10.1021/jacs.6c07628
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              Text: 2026 Jul 15
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