Observation of one-dimensional, charged domain walls in ferroelectric ZrO2.

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Title: Observation of one-dimensional, charged domain walls in ferroelectric ZrO2.
Authors: Zhong, Hai (AUTHOR), Wang, Shiyu (AUTHOR), Zhang, Qinghua (AUTHOR), Liu, Zhuohui (AUTHOR), Xie, Donggang (AUTHOR), Lu, Jiali (AUTHOR), Jin, Shifeng (AUTHOR), Zhang, Shufang (AUTHOR), Guo, Er-jia (AUTHOR), He, Meng (AUTHOR), Wang, Can (AUTHOR), Gu, Lin (AUTHOR), Yang, Guozhen (AUTHOR), Jin, Kui-juan (AUTHOR), Ge, Chen (AUTHOR)
Source: Science. 1/22/2026, Vol. 391 Issue 6783, p407-411. 5p.
Subjects: Zirconium oxide, Ferroelectric crystals, Dimensional analysis, Electric field effects, Nanoscience
Abstract: Ferroelectric charged domain walls (CDWs) with nanoscale thickness and bound charges are typically viewed as ultrathin, reconfigurable, and highly conductive two-dimensional components for domain wall nanoelectronics. Dimensional confinement of such polar topological structures has the potential to increase device density and unlock novel functionalities. We report 180° head-to-head and tail-to-tail CDWs exhibiting one-dimensional (1D) characteristics. These 1D CDWs are confined within the polar layers of ferroelectric ZrO2 and have atomic-scale dimensions in both width and thickness. Quantitative analysis unveils a distinct screening mechanism of these walls whereby bound polarization charges are compensated by self-balancing oxygen occupancy. We demonstrate electric field–driven manipulation of these 1D CDWs, revealing the microscopic coupling between polarization switching and oxygen-ion transport. Editor's summary: Freestanding ferroelectric zirconium dioxide thin films exhibit one-dimensional charged domain walls (1D CDWs) with head-to-head and tail-to-tail polarization. Zhong et al. imaged these 5-nanometer films and found that an alternating arrangement of nonpolar and polar oxygen ions formed 2D polar sheets that confined the 1D CDWs. Electric-field manipulation of these domain walls led to transport of oxygen ions. —Phil Szuromi [ABSTRACT FROM AUTHOR]
Copyright of Science is the property of American Association for the Advancement of Science and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Label: Title
  Group: Ti
  Data: Observation of one-dimensional, charged domain walls in ferroelectric ZrO<subscript>2</subscript>.
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  Label: Authors
  Group: Au
  Data: <searchLink fieldCode="AR" term="%22Zhong%2C+Hai%22">Zhong, Hai</searchLink> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Wang%2C+Shiyu%22">Wang, Shiyu</searchLink> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Zhang%2C+Qinghua%22">Zhang, Qinghua</searchLink> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Liu%2C+Zhuohui%22">Liu, Zhuohui</searchLink> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Xie%2C+Donggang%22">Xie, Donggang</searchLink> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Lu%2C+Jiali%22">Lu, Jiali</searchLink> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Jin%2C+Shifeng%22">Jin, Shifeng</searchLink> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Zhang%2C+Shufang%22">Zhang, Shufang</searchLink> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Guo%2C+Er-jia%22">Guo, Er-jia</searchLink> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22He%2C+Meng%22">He, Meng</searchLink> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Wang%2C+Can%22">Wang, Can</searchLink> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Gu%2C+Lin%22">Gu, Lin</searchLink> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Yang%2C+Guozhen%22">Yang, Guozhen</searchLink> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Jin%2C+Kui-juan%22">Jin, Kui-juan</searchLink> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Ge%2C+Chen%22">Ge, Chen</searchLink> (AUTHOR)
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  Data: <searchLink fieldCode="JN" term="%22Science%22">Science</searchLink>. 1/22/2026, Vol. 391 Issue 6783, p407-411. 5p.
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  Data: <searchLink fieldCode="DE" term="%22Zirconium+oxide%22">Zirconium oxide</searchLink><br /><searchLink fieldCode="DE" term="%22Ferroelectric+crystals%22">Ferroelectric crystals</searchLink><br /><searchLink fieldCode="DE" term="%22Dimensional+analysis%22">Dimensional analysis</searchLink><br /><searchLink fieldCode="DE" term="%22Electric+field+effects%22">Electric field effects</searchLink><br /><searchLink fieldCode="DE" term="%22Nanoscience%22">Nanoscience</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Ferroelectric charged domain walls (CDWs) with nanoscale thickness and bound charges are typically viewed as ultrathin, reconfigurable, and highly conductive two-dimensional components for domain wall nanoelectronics. Dimensional confinement of such polar topological structures has the potential to increase device density and unlock novel functionalities. We report 180° head-to-head and tail-to-tail CDWs exhibiting one-dimensional (1D) characteristics. These 1D CDWs are confined within the polar layers of ferroelectric ZrO2 and have atomic-scale dimensions in both width and thickness. Quantitative analysis unveils a distinct screening mechanism of these walls whereby bound polarization charges are compensated by self-balancing oxygen occupancy. We demonstrate electric field–driven manipulation of these 1D CDWs, revealing the microscopic coupling between polarization switching and oxygen-ion transport. Editor's summary: Freestanding ferroelectric zirconium dioxide thin films exhibit one-dimensional charged domain walls (1D CDWs) with head-to-head and tail-to-tail polarization. Zhong et al. imaged these 5-nanometer films and found that an alternating arrangement of nonpolar and polar oxygen ions formed 2D polar sheets that confined the 1D CDWs. Electric-field manipulation of these domain walls led to transport of oxygen ions. —Phil Szuromi [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Science is the property of American Association for the Advancement of Science and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1126/science.aeb7280
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      – Code: eng
        Text: English
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        PageCount: 5
        StartPage: 407
    Subjects:
      – SubjectFull: Zirconium oxide
        Type: general
      – SubjectFull: Ferroelectric crystals
        Type: general
      – SubjectFull: Dimensional analysis
        Type: general
      – SubjectFull: Electric field effects
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      – SubjectFull: Nanoscience
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      – TitleFull: Observation of one-dimensional, charged domain walls in ferroelectric ZrO2.
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              Text: 1/22/2026
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