Species Distribution Diagrams in the Copper -- Ammonia System: An Updated and Expanded Demonstration Illustrating Complex Equilibria.

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Title: Species Distribution Diagrams in the Copper -- Ammonia System: An Updated and Expanded Demonstration Illustrating Complex Equilibria.
Authors: Johnson, Adam R., McQueen, Tyrel M., Rodolfa, Kit T.
Source: Journal of Chemical Education. Mar2005, Vol. 82 Issue 3, p408-414. 7p.
Subjects: CHEMICAL reactions, CHEMICAL equilibrium, COMPLEX ions, ACID-base chemistry, SOLUBILITY, ALGEBRA, EQUATIONS
Abstract: The article discusses species distribution diagrams in the Copper-Ammonia System. This seemingly simple system encompasses three major classes of equilibrium chemistry commonly taught in inorganic chemistry, which are acid-base, complex ion formation and solubility. The updated demonstration emphasizes the fact that coupled equilibria, while complicated and difficult to solve exactly, can be readily understood and explained by simple algebraic equations. It is also a useful summative demonstration that could end an entire unit on chemical equilibria. Selected portions of this demonstration have been used successfully at both the introductory and advanced undergraduate level.
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  Data: Species Distribution Diagrams in the Copper -- Ammonia System: An Updated and Expanded Demonstration Illustrating Complex Equilibria.
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  Data: <searchLink fieldCode="AR" term="%22Johnson%2C+Adam+R%2E%22">Johnson, Adam R.</searchLink><br /><searchLink fieldCode="AR" term="%22McQueen%2C+Tyrel+M%2E%22">McQueen, Tyrel M.</searchLink><br /><searchLink fieldCode="AR" term="%22Rodolfa%2C+Kit+T%2E%22">Rodolfa, Kit T.</searchLink>
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  Data: <searchLink fieldCode="JN" term="%22Journal+of+Chemical+Education%22">Journal of Chemical Education</searchLink>. Mar2005, Vol. 82 Issue 3, p408-414. 7p.
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  Data: <searchLink fieldCode="DE" term="%22CHEMICAL+reactions%22">CHEMICAL reactions</searchLink><br /><searchLink fieldCode="DE" term="%22CHEMICAL+equilibrium%22">CHEMICAL equilibrium</searchLink><br /><searchLink fieldCode="DE" term="%22COMPLEX+ions%22">COMPLEX ions</searchLink><br /><searchLink fieldCode="DE" term="%22ACID-base+chemistry%22">ACID-base chemistry</searchLink><br /><searchLink fieldCode="DE" term="%22SOLUBILITY%22">SOLUBILITY</searchLink><br /><searchLink fieldCode="DE" term="%22ALGEBRA%22">ALGEBRA</searchLink><br /><searchLink fieldCode="DE" term="%22EQUATIONS%22">EQUATIONS</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: The article discusses species distribution diagrams in the Copper-Ammonia System. This seemingly simple system encompasses three major classes of equilibrium chemistry commonly taught in inorganic chemistry, which are acid-base, complex ion formation and solubility. The updated demonstration emphasizes the fact that coupled equilibria, while complicated and difficult to solve exactly, can be readily understood and explained by simple algebraic equations. It is also a useful summative demonstration that could end an entire unit on chemical equilibria. Selected portions of this demonstration have been used successfully at both the introductory and advanced undergraduate level.
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RecordInfo BibRecord:
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    Identifiers:
      – Type: doi
        Value: 10.1021/ed082p408
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      – Code: eng
        Text: English
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      Pagination:
        PageCount: 7
        StartPage: 408
    Subjects:
      – SubjectFull: CHEMICAL reactions
        Type: general
      – SubjectFull: CHEMICAL equilibrium
        Type: general
      – SubjectFull: COMPLEX ions
        Type: general
      – SubjectFull: ACID-base chemistry
        Type: general
      – SubjectFull: SOLUBILITY
        Type: general
      – SubjectFull: ALGEBRA
        Type: general
      – SubjectFull: EQUATIONS
        Type: general
    Titles:
      – TitleFull: Species Distribution Diagrams in the Copper -- Ammonia System: An Updated and Expanded Demonstration Illustrating Complex Equilibria.
        Type: main
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            NameFull: Johnson, Adam R.
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            NameFull: McQueen, Tyrel M.
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            NameFull: Rodolfa, Kit T.
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            – D: 01
              M: 03
              Text: Mar2005
              Type: published
              Y: 2005
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              Value: 82
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              Value: 3
          Titles:
            – TitleFull: Journal of Chemical Education
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