Mechanistic Investigation of Enediyne-Connected Amino Ester Rearrangement. Theoretical Rationale for the Exclusive Preference for 1,6- or 1,5-Hydrogen Atom Transfer Depending on the Substrate. A Potential Route to Chiral Naphthoazepines.

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Title: Mechanistic Investigation of Enediyne-Connected Amino Ester Rearrangement. Theoretical Rationale for the Exclusive Preference for 1,6- or 1,5-Hydrogen Atom Transfer Depending on the Substrate. A Potential Route to Chiral Naphthoazepines.
Authors: Campolo, Damien1, Gaudel-Siri, Anouk1 anouk.siri@uiv-cezanne.fr, Mondal, Shovan1, Siri, Didier1, Besson, Eric1, Vanthuyne, Nicolas2, Nechab, Malek1 malek.nechab@univ-provence.fr, Bertrand, Michele P.1 michele.bertrand@univ-cezanne.fr
Source: Journal of Organic Chemistry. 3/16/2012, Vol. 77 Issue 6, p2773-2783. 11p.
Database: Academic Search Ultimate
Description
ISSN:00223263
DOI:10.1021/jo202580y