Bibliographic Details
| Title: |
Syntheses, crystal structures and properties of series of 4d–4f ln(III)–Ag(I) heterometallic coordination polymers. |
| Authors: |
Ran, Xing-Rui1, Wang, Ning2, Xie, Wei-Ping1, Xiong, Yan-Ju1, Cheng, Qian1, Long, Yi2, Yue, Shan-Tang1,3 yuesht@scnu.edu.cn, Liu, Ying-Liang4 |
| Source: |
Journal of Solid State Chemistry. May2015, Vol. 225, p24-30. 7p. |
| Subjects: |
Crystal structure, Coordination polymers synthesis, Parameter estimation, X-ray diffraction, Thermogravimetry |
| Abstract: |
By control of the experimental parameters such as ligands, pH value and reacting temperature, series of three-dimensional (3D) 4d–4f Ln (III)–Ag(I) porous coordination polymers (PCPs) with interesting chain-layer construction, namely, {[ Ln III Ag I (na)(ina)(ox)]·2(H 2 O)} n [ Ln =Sm( 1 ), Eu( 2 ), Gd( 3 ), Tb( 4 ), Dy( 5 ), Ho( 6 ), Y( 7 ), Yb( 8 )], have been successfully synthesized under hydrothermal conditions and structurally characterized. All the complexes are characterized by elemental analyses, FT-IR spectroscopy, Powder X-ray diffraction (PXRD) and thermogravimetric analyses (TGA). Furthermore, the luminescence properties of compounds 2 and 4 and the magsnetic properties of complexes 3 and 5 were also investigated in detail. [ABSTRACT FROM AUTHOR] |
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| Database: |
Engineering Source |
