Syntheses, crystal structures and properties of series of 4d–4f ln(III)–Ag(I) heterometallic coordination polymers.

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Title: Syntheses, crystal structures and properties of series of 4d–4f ln(III)–Ag(I) heterometallic coordination polymers.
Authors: Ran, Xing-Rui1, Wang, Ning2, Xie, Wei-Ping1, Xiong, Yan-Ju1, Cheng, Qian1, Long, Yi2, Yue, Shan-Tang1,3 yuesht@scnu.edu.cn, Liu, Ying-Liang4
Source: Journal of Solid State Chemistry. May2015, Vol. 225, p24-30. 7p.
Subjects: Crystal structure, Coordination polymers synthesis, Parameter estimation, X-ray diffraction, Thermogravimetry
Abstract: By control of the experimental parameters such as ligands, pH value and reacting temperature, series of three-dimensional (3D) 4d–4f Ln (III)–Ag(I) porous coordination polymers (PCPs) with interesting chain-layer construction, namely, {[ Ln III Ag I (na)(ina)(ox)]·2(H 2 O)} n [ Ln =Sm( 1 ), Eu( 2 ), Gd( 3 ), Tb( 4 ), Dy( 5 ), Ho( 6 ), Y( 7 ), Yb( 8 )], have been successfully synthesized under hydrothermal conditions and structurally characterized. All the complexes are characterized by elemental analyses, FT-IR spectroscopy, Powder X-ray diffraction (PXRD) and thermogravimetric analyses (TGA). Furthermore, the luminescence properties of compounds 2 and 4 and the magsnetic properties of complexes 3 and 5 were also investigated in detail. [ABSTRACT FROM AUTHOR]
Copyright of Journal of Solid State Chemistry is the property of Academic Press Inc. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Syntheses, crystal structures and properties of series of 4d–4f ln(III)–Ag(I) heterometallic coordination polymers.
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  Data: <searchLink fieldCode="JN" term="%22Journal+of+Solid+State+Chemistry%22">Journal of Solid State Chemistry</searchLink>. May2015, Vol. 225, p24-30. 7p.
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  Data: <searchLink fieldCode="DE" term="%22Crystal+structure%22">Crystal structure</searchLink><br /><searchLink fieldCode="DE" term="%22Coordination+polymers+synthesis%22">Coordination polymers synthesis</searchLink><br /><searchLink fieldCode="DE" term="%22Parameter+estimation%22">Parameter estimation</searchLink><br /><searchLink fieldCode="DE" term="%22X-ray+diffraction%22">X-ray diffraction</searchLink><br /><searchLink fieldCode="DE" term="%22Thermogravimetry%22">Thermogravimetry</searchLink>
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  Label: Abstract
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  Data: By control of the experimental parameters such as ligands, pH value and reacting temperature, series of three-dimensional (3D) 4d–4f Ln (III)–Ag(I) porous coordination polymers (PCPs) with interesting chain-layer construction, namely, {[ Ln III Ag I (na)(ina)(ox)]·2(H 2 O)} n [ Ln =Sm( 1 ), Eu( 2 ), Gd( 3 ), Tb( 4 ), Dy( 5 ), Ho( 6 ), Y( 7 ), Yb( 8 )], have been successfully synthesized under hydrothermal conditions and structurally characterized. All the complexes are characterized by elemental analyses, FT-IR spectroscopy, Powder X-ray diffraction (PXRD) and thermogravimetric analyses (TGA). Furthermore, the luminescence properties of compounds 2 and 4 and the magsnetic properties of complexes 3 and 5 were also investigated in detail. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Journal of Solid State Chemistry is the property of Academic Press Inc. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
  BibEntity:
    Identifiers:
      – Type: doi
        Value: 10.1016/j.jssc.2014.11.022
    Languages:
      – Code: eng
        Text: English
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      Pagination:
        PageCount: 7
        StartPage: 24
    Subjects:
      – SubjectFull: Crystal structure
        Type: general
      – SubjectFull: Coordination polymers synthesis
        Type: general
      – SubjectFull: Parameter estimation
        Type: general
      – SubjectFull: X-ray diffraction
        Type: general
      – SubjectFull: Thermogravimetry
        Type: general
    Titles:
      – TitleFull: Syntheses, crystal structures and properties of series of 4d–4f ln(III)–Ag(I) heterometallic coordination polymers.
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            NameFull: Ran, Xing-Rui
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            NameFull: Wang, Ning
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            NameFull: Xie, Wei-Ping
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            NameFull: Xiong, Yan-Ju
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            NameFull: Cheng, Qian
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            NameFull: Long, Yi
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            NameFull: Yue, Shan-Tang
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            NameFull: Liu, Ying-Liang
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            – D: 01
              M: 05
              Text: May2015
              Type: published
              Y: 2015
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              Value: 225
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            – TitleFull: Journal of Solid State Chemistry
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