Stereochemistry of the thermal isomerization of 1-ethenyl-7-exo-phenylbicyclo[4.1.0]heptane to...

Saved in:
Bibliographic Details
Title: Stereochemistry of the thermal isomerization of 1-ethenyl-7-exo-phenylbicyclo[4.1.0]heptane to...
Authors: Baldwin, John E., Bonacorsi Jr., Samuel J., Burrell, Richard C.
Source: Journal of Organic Chemistry. 07/10/98, Vol. 63 Issue 14, p4721. 5p. 8 Diagrams.
Subjects: Cyclopropane, Cyclophanes
Abstract: Proposes two alternatives for progress leading anatarafacially from a vinylcyclopropane to a cyclopentene product. Background information on the first report of the thermal rearrangement of vinylcyclopropane to cyclopentene; Difficulties regarding the early attempts to determine reaction stereochemistry for selected vinylcyclopropane rearrangement.
Database: Engineering Source
Description
Abstract:Proposes two alternatives for progress leading anatarafacially from a vinylcyclopropane to a cyclopentene product. Background information on the first report of the thermal rearrangement of vinylcyclopropane to cyclopentene; Difficulties regarding the early attempts to determine reaction stereochemistry for selected vinylcyclopropane rearrangement.
ISSN:00223263
DOI:10.1021/jo980420v