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Low Temperature Syntheses and Reactivity of Cu2O2Active-Site Models.

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Title: Low Temperature Syntheses and Reactivity of Cu2O2Active-Site Models.
Authors: Cooper Citek1, Sonja Herres-Pawlis1, T. Daniel P. Stack1
Source: Accounts of Chemical Research. Aug2015, Vol. 48 Issue 8, p2424-2433. 10p.
Subjects: Reactivity (Chemistry), Oxidation, Enzymes, Biosynthesis, Low temperatures, Copper oxide, Oxidants & Antioxidants: Ultrastructure & Molecular Biology Protocols (Book)
Abstract: Nature’sfacility with dioxygen outmatches modern chemistryin the oxidation and oxygenation of materials and substrates for biosynthesisand cellular metabolism. The Earth’s most abundant naturallyoccurring oxidant isfranklypoorly understood and controlled,and thus underused. Copper-based enzyme metallocofactors are ubiquitousto the efficient consumption of dioxygen by all domains of life. Overthe last several decades, we have joined many research groups in thestudy of copper- and dioxygen-dependent enzymes through close investigationof synthetically derived, small-molecule active-site analogs. Simplecopper-dioxygen clusters bearing structural and spectroscopic similarityto dioxygen-activating enzymes can be probed for their fundamentalgeometrical, electronic, and reactive properties using the tools availableto inorganic and synthetic chemistry. [ABSTRACT FROM AUTHOR]
Copyright of Accounts of Chemical Research is the property of American Chemical Society and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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DbLabel: Engineering Source
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  Data: Low Temperature Syntheses and Reactivity of Cu2O2Active-Site Models.
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  Data: <searchLink fieldCode="AR" term="%22Cooper+Citek%22">Cooper Citek</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Sonja+Herres-Pawlis%22">Sonja Herres-Pawlis</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22T%2E+Daniel+P%2E+Stack%22">T. Daniel P. Stack</searchLink><relatesTo>1</relatesTo>
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  Data: <searchLink fieldCode="JN" term="%22Accounts+of+Chemical+Research%22">Accounts of Chemical Research</searchLink>. Aug2015, Vol. 48 Issue 8, p2424-2433. 10p.
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  Data: <searchLink fieldCode="DE" term="%22Reactivity+%28Chemistry%29%22">Reactivity (Chemistry)</searchLink><br /><searchLink fieldCode="DE" term="%22Oxidation%22">Oxidation</searchLink><br /><searchLink fieldCode="DE" term="%22Enzymes%22">Enzymes</searchLink><br /><searchLink fieldCode="DE" term="%22Biosynthesis%22">Biosynthesis</searchLink><br /><searchLink fieldCode="DE" term="%22Low+temperatures%22">Low temperatures</searchLink><br /><searchLink fieldCode="DE" term="%22Copper+oxide%22">Copper oxide</searchLink><br /><searchLink fieldCode="DE" term="%22Oxidants+%26+Antioxidants%3A+Ultrastructure+%26+Molecular+Biology+Protocols+%28Book%29%22">Oxidants & Antioxidants: Ultrastructure & Molecular Biology Protocols (Book)</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Nature’sfacility with dioxygen outmatches modern chemistryin the oxidation and oxygenation of materials and substrates for biosynthesisand cellular metabolism. The Earth’s most abundant naturallyoccurring oxidant isfranklypoorly understood and controlled,and thus underused. Copper-based enzyme metallocofactors are ubiquitousto the efficient consumption of dioxygen by all domains of life. Overthe last several decades, we have joined many research groups in thestudy of copper- and dioxygen-dependent enzymes through close investigationof synthetically derived, small-molecule active-site analogs. Simplecopper-dioxygen clusters bearing structural and spectroscopic similarityto dioxygen-activating enzymes can be probed for their fundamentalgeometrical, electronic, and reactive properties using the tools availableto inorganic and synthetic chemistry. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Accounts of Chemical Research is the property of American Chemical Society and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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      – Type: doi
        Value: 10.1021/acs.accounts.5b00220
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      – Code: eng
        Text: English
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        Type: general
      – SubjectFull: Oxidation
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      – SubjectFull: Enzymes
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      – SubjectFull: Biosynthesis
        Type: general
      – SubjectFull: Low temperatures
        Type: general
      – SubjectFull: Copper oxide
        Type: general
      – SubjectFull: Oxidants & Antioxidants: Ultrastructure & Molecular Biology Protocols (Book)
        Type: general
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      – TitleFull: Low Temperature Syntheses and Reactivity of Cu2O2Active-Site Models.
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            NameFull: T. Daniel P. Stack
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            – D: 18
              M: 08
              Text: Aug2015
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