Bibliographic Details
| Title: |
Mild regiospecific alcoholysis and aminolysis of epoxides catalyzed by zirconium(IV) oxynitrate. |
| Authors: |
Shinde, Sandip S.1 ss.shinde@ncl.res.in, Said, Madhukar S.1, Surwase, Trupti B.1, Kumar, Pradeep1 |
| Source: |
Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry. Oct2015, Vol. 56 Issue 43, p5916-5919. 4p. |
| Subjects: |
Alcoholysis, Epoxy compounds, Zirconium compounds, Catalysis, Ring-opening reactions, Aliphatic amines |
| Abstract: |
A regiospecific method for the ring-opening reaction of epoxides by the primary, secondary, tertiary alcohols, and aryl, aliphatic amines has been developed using non-toxic metal nitrate salt as a catalyst. The best results were obtained using zirconium(IV) oxynitrate among the various screened metal nitrate salts. The reported protocol works efficiently for styrene epoxide and aliphatic as well. [ABSTRACT FROM AUTHOR] |
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| Database: |
Engineering Source |
