Mild regiospecific alcoholysis and aminolysis of epoxides catalyzed by zirconium(IV) oxynitrate.
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| Title: | Mild regiospecific alcoholysis and aminolysis of epoxides catalyzed by zirconium(IV) oxynitrate. |
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| Authors: | Shinde, Sandip S.1 ss.shinde@ncl.res.in, Said, Madhukar S.1, Surwase, Trupti B.1, Kumar, Pradeep1 |
| Source: | Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry. Oct2015, Vol. 56 Issue 43, p5916-5919. 4p. |
| Subjects: | Alcoholysis, Epoxy compounds, Zirconium compounds, Catalysis, Ring-opening reactions, Aliphatic amines |
| Abstract: | A regiospecific method for the ring-opening reaction of epoxides by the primary, secondary, tertiary alcohols, and aryl, aliphatic amines has been developed using non-toxic metal nitrate salt as a catalyst. The best results were obtained using zirconium(IV) oxynitrate among the various screened metal nitrate salts. The reported protocol works efficiently for styrene epoxide and aliphatic as well. [ABSTRACT FROM AUTHOR] |
| Copyright of Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry is the property of Pergamon Press - An Imprint of Elsevier Science and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
| Database: | Engineering Source |
| FullText | Text: Availability: 0 |
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| Header | DbId: egs DbLabel: Engineering Source An: 109980144 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
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| Items | – Name: Title Label: Title Group: Ti Data: Mild regiospecific alcoholysis and aminolysis of epoxides catalyzed by zirconium(IV) oxynitrate. – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22Shinde%2C+Sandip+S%2E%22">Shinde, Sandip S.</searchLink><relatesTo>1</relatesTo><i> ss.shinde@ncl.res.in</i><br /><searchLink fieldCode="AR" term="%22Said%2C+Madhukar+S%2E%22">Said, Madhukar S.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Surwase%2C+Trupti+B%2E%22">Surwase, Trupti B.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Kumar%2C+Pradeep%22">Kumar, Pradeep</searchLink><relatesTo>1</relatesTo> – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22Tetrahedron+Letters%3A+International+Organ+for+the+Rapid+Publication+of+Preliminary+Communications+in+Organic+Chemistry%22">Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry</searchLink>. Oct2015, Vol. 56 Issue 43, p5916-5919. 4p. – Name: Subject Label: Subjects Group: Su Data: <searchLink fieldCode="DE" term="%22Alcoholysis%22">Alcoholysis</searchLink><br /><searchLink fieldCode="DE" term="%22Epoxy+compounds%22">Epoxy compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Zirconium+compounds%22">Zirconium compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Catalysis%22">Catalysis</searchLink><br /><searchLink fieldCode="DE" term="%22Ring-opening+reactions%22">Ring-opening reactions</searchLink><br /><searchLink fieldCode="DE" term="%22Aliphatic+amines%22">Aliphatic amines</searchLink> – Name: Abstract Label: Abstract Group: Ab Data: A regiospecific method for the ring-opening reaction of epoxides by the primary, secondary, tertiary alcohols, and aryl, aliphatic amines has been developed using non-toxic metal nitrate salt as a catalyst. The best results were obtained using zirconium(IV) oxynitrate among the various screened metal nitrate salts. The reported protocol works efficiently for styrene epoxide and aliphatic as well. [ABSTRACT FROM AUTHOR] – Name: AbstractSuppliedCopyright Label: Group: Ab Data: <i>Copyright of Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry is the property of Pergamon Press - An Imprint of Elsevier Science and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.) |
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| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.1016/j.tetlet.2015.09.031 Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 4 StartPage: 5916 Subjects: – SubjectFull: Alcoholysis Type: general – SubjectFull: Epoxy compounds Type: general – SubjectFull: Zirconium compounds Type: general – SubjectFull: Catalysis Type: general – SubjectFull: Ring-opening reactions Type: general – SubjectFull: Aliphatic amines Type: general Titles: – TitleFull: Mild regiospecific alcoholysis and aminolysis of epoxides catalyzed by zirconium(IV) oxynitrate. Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Shinde, Sandip S. – PersonEntity: Name: NameFull: Said, Madhukar S. – PersonEntity: Name: NameFull: Surwase, Trupti B. – PersonEntity: Name: NameFull: Kumar, Pradeep IsPartOfRelationships: – BibEntity: Dates: – D: 21 M: 10 Text: Oct2015 Type: published Y: 2015 Identifiers: – Type: issn-print Value: 00404039 Numbering: – Type: volume Value: 56 – Type: issue Value: 43 Titles: – TitleFull: Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry Type: main |
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