Mild regiospecific alcoholysis and aminolysis of epoxides catalyzed by zirconium(IV) oxynitrate.

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Title: Mild regiospecific alcoholysis and aminolysis of epoxides catalyzed by zirconium(IV) oxynitrate.
Authors: Shinde, Sandip S.1 ss.shinde@ncl.res.in, Said, Madhukar S.1, Surwase, Trupti B.1, Kumar, Pradeep1
Source: Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry. Oct2015, Vol. 56 Issue 43, p5916-5919. 4p.
Subjects: Alcoholysis, Epoxy compounds, Zirconium compounds, Catalysis, Ring-opening reactions, Aliphatic amines
Abstract: A regiospecific method for the ring-opening reaction of epoxides by the primary, secondary, tertiary alcohols, and aryl, aliphatic amines has been developed using non-toxic metal nitrate salt as a catalyst. The best results were obtained using zirconium(IV) oxynitrate among the various screened metal nitrate salts. The reported protocol works efficiently for styrene epoxide and aliphatic as well. [ABSTRACT FROM AUTHOR]
Copyright of Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry is the property of Pergamon Press - An Imprint of Elsevier Science and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Mild regiospecific alcoholysis and aminolysis of epoxides catalyzed by zirconium(IV) oxynitrate.
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  Data: <searchLink fieldCode="DE" term="%22Alcoholysis%22">Alcoholysis</searchLink><br /><searchLink fieldCode="DE" term="%22Epoxy+compounds%22">Epoxy compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Zirconium+compounds%22">Zirconium compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Catalysis%22">Catalysis</searchLink><br /><searchLink fieldCode="DE" term="%22Ring-opening+reactions%22">Ring-opening reactions</searchLink><br /><searchLink fieldCode="DE" term="%22Aliphatic+amines%22">Aliphatic amines</searchLink>
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  Data: A regiospecific method for the ring-opening reaction of epoxides by the primary, secondary, tertiary alcohols, and aryl, aliphatic amines has been developed using non-toxic metal nitrate salt as a catalyst. The best results were obtained using zirconium(IV) oxynitrate among the various screened metal nitrate salts. The reported protocol works efficiently for styrene epoxide and aliphatic as well. [ABSTRACT FROM AUTHOR]
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  Data: <i>Copyright of Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry is the property of Pergamon Press - An Imprint of Elsevier Science and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1016/j.tetlet.2015.09.031
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        Text: English
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        Type: general
      – SubjectFull: Epoxy compounds
        Type: general
      – SubjectFull: Zirconium compounds
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      – SubjectFull: Catalysis
        Type: general
      – SubjectFull: Ring-opening reactions
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      – SubjectFull: Aliphatic amines
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      – TitleFull: Mild regiospecific alcoholysis and aminolysis of epoxides catalyzed by zirconium(IV) oxynitrate.
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              Text: Oct2015
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