Bibliographic Details
| Title: |
A synthetic and crystal structure study of a collection of coordination polymers based on alkaline aroylhydrazonates. |
| Authors: |
Specklin, David1, Mameri, Samir1,2 mameri@unistra.fr, Loukopoulos, Edward3, Kostakis, George E.3, Welter, Richard4 welter@unistra.fr |
| Source: |
Polyhedron. Nov2015, Vol. 100, p359-372. 14p. |
| Subjects: |
Crystal structure, Coordination polymers, Hydrazones, Alkaline earth compounds, Chemical reactions |
| Abstract: |
The reactions of two aroylhydrazone ligands H 2 L S and H 2 L Ac with alkaline Li(I), Na(I), K(I) and Ba(II) metal ions afforded nine new coordination polymers with different dimensionalities. These illustrate the ionic radii, the ligand substitution and the solvent influence on the formation of the final product. Interestingly, one of them shows porous structure with a 40% unoccupied volume. [ABSTRACT FROM AUTHOR] |
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| Database: |
Engineering Source |
