A synthetic and crystal structure study of a collection of coordination polymers based on alkaline aroylhydrazonates.
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| Title: | A synthetic and crystal structure study of a collection of coordination polymers based on alkaline aroylhydrazonates. |
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| Authors: | Specklin, David1, Mameri, Samir1,2 mameri@unistra.fr, Loukopoulos, Edward3, Kostakis, George E.3, Welter, Richard4 welter@unistra.fr |
| Source: | Polyhedron. Nov2015, Vol. 100, p359-372. 14p. |
| Subjects: | Crystal structure, Coordination polymers, Hydrazones, Alkaline earth compounds, Chemical reactions |
| Abstract: | The reactions of two aroylhydrazone ligands H 2 L S and H 2 L Ac with alkaline Li(I), Na(I), K(I) and Ba(II) metal ions afforded nine new coordination polymers with different dimensionalities. These illustrate the ionic radii, the ligand substitution and the solvent influence on the formation of the final product. Interestingly, one of them shows porous structure with a 40% unoccupied volume. [ABSTRACT FROM AUTHOR] |
| Copyright of Polyhedron is the property of Pergamon Press - An Imprint of Elsevier Science and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
| Database: | Engineering Source |
| FullText | Text: Availability: 0 |
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| Header | DbId: egs DbLabel: Engineering Source An: 110822604 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
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| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.1016/j.poly.2015.08.013 Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 14 StartPage: 359 Subjects: – SubjectFull: Crystal structure Type: general – SubjectFull: Coordination polymers Type: general – SubjectFull: Hydrazones Type: general – SubjectFull: Alkaline earth compounds Type: general – SubjectFull: Chemical reactions Type: general Titles: – TitleFull: A synthetic and crystal structure study of a collection of coordination polymers based on alkaline aroylhydrazonates. Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Specklin, David – PersonEntity: Name: NameFull: Mameri, Samir – PersonEntity: Name: NameFull: Loukopoulos, Edward – PersonEntity: Name: NameFull: Kostakis, George E. – PersonEntity: Name: NameFull: Welter, Richard IsPartOfRelationships: – BibEntity: Dates: – D: 04 M: 11 Text: Nov2015 Type: published Y: 2015 Identifiers: – Type: issn-print Value: 02775387 Numbering: – Type: volume Value: 100 Titles: – TitleFull: Polyhedron Type: main |
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