Bibliographic Details
| Title: |
Iron cyclopentadienone complexes derived from C2-symmetric bis-propargylic alcohols; preparation and applications to catalysis. |
| Authors: |
Hodgkinson, Roy1, Del Grosso, Alessandro1, Clarkson, Guy1, Wills, Martin1 |
| Source: |
Dalton Transactions: An International Journal of Inorganic Chemistry. 3/7/2016, Vol. 45 Issue 9, p3992-4005. 14p. |
| Subjects: |
Iron compound synthesis, Cyclopentadiene derivatives, Propargyl alcohol, Carbonyl compounds, Alcohol oxidation, Reduction of ketones, Catalytic activity |
| Abstract: |
A series of complexes containing the iron-cyclopentadienone structure were prepared by cyclising bis-propargylic alcohols and their derivatives with iron pentacarbonyl. The resulting complexes were characterised and tested in the catalysis of ketone reduction and alcohol oxidation. The complexes are competent catalysts for ketone reduction and alcohol oxidations. [ABSTRACT FROM AUTHOR] |
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| Database: |
Engineering Source |
