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Tuning of the reaction parameters to optimize allylic oxidation of cyclohexene catalyzed by zeolite-Y entrapped transition metal complexes.

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Title:	Tuning of the reaction parameters to optimize allylic oxidation of cyclohexene catalyzed by zeolite-Y entrapped transition metal complexes.
Authors:	Godhani, Dinesh R.¹ drgodhani@yahoo.com, Nakum, Haresh D.¹, Parmar, Digvijaysinh K.¹, Mehta, Jignasu P.¹, Desai, Nisheeth C.¹
Source:	Journal of Molecular Catalysis A: Chemistry. May2016, Vol. 415, p37-55. 19p.
Subjects:	Transition metal complexes, Oxidation, Cyclohexene, Zeolite catalysts, Molecular size, Schiff bases
Abstract:	The synthetic protocols for entrapment of transition metal complexes reported here are to expand the diversity in catalysis made possible by the ability of microporous solid to select reactants, transition states, and products based on their molecular size. Herein, we report a synthetic route for the entrapment of transition metal complexes within the nanopores of zeolite-Y. The complexes of transition metals [M = Fe(II), VO(IV)] with Schiff base ligands that are synthesized by simple condensation of 2-hydroxyacetophenone and/or 2-hydroxy-5-chloroacetophenone with ethylenediamine have been entrapped within nanopores of zeolite-Y by flexible ligand method. These materials have been characterized by various physicochemical and spectroscopic techniques such as ICP-OES, FT-IR, 1 H and 13 C NMR, elemental analyzes, and UV–vis electronic spectral studies, BET, TGA, scanning electron micrographs (SEMs), X-ray diffraction patterns (XRD), conductivity, magnetic susceptibilities as well as AAS. These synthesized catalysts have been utilized as heterogeneous catalysts for liquid phase oxidation of cyclohexene. The reaction parameters have been tuned to optimize higher cyclohexene conversion (%) along with higher selectivity towards the formation of corresponding allylic products. These catalysts were recovered and reused for three times without remarkable loss of activity. Moreover, the intermediate species involved during the catalytic oxidation reaction was synthesized and identified by FTIR and UV–vis spectroscopy. [ABSTRACT FROM AUTHOR]
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Database:	Engineering Source

Description
Abstract:	The synthetic protocols for entrapment of transition metal complexes reported here are to expand the diversity in catalysis made possible by the ability of microporous solid to select reactants, transition states, and products based on their molecular size. Herein, we report a synthetic route for the entrapment of transition metal complexes within the nanopores of zeolite-Y. The complexes of transition metals [M = Fe(II), VO(IV)] with Schiff base ligands that are synthesized by simple condensation of 2-hydroxyacetophenone and/or 2-hydroxy-5-chloroacetophenone with ethylenediamine have been entrapped within nanopores of zeolite-Y by flexible ligand method. These materials have been characterized by various physicochemical and spectroscopic techniques such as ICP-OES, FT-IR, 1 H and 13 C NMR, elemental analyzes, and UV–vis electronic spectral studies, BET, TGA, scanning electron micrographs (SEMs), X-ray diffraction patterns (XRD), conductivity, magnetic susceptibilities as well as AAS. These synthesized catalysts have been utilized as heterogeneous catalysts for liquid phase oxidation of cyclohexene. The reaction parameters have been tuned to optimize higher cyclohexene conversion (%) along with higher selectivity towards the formation of corresponding allylic products. These catalysts were recovered and reused for three times without remarkable loss of activity. Moreover, the intermediate species involved during the catalytic oxidation reaction was synthesized and identified by FTIR and UV–vis spectroscopy. [ABSTRACT FROM AUTHOR]
ISSN:	13811169
DOI:	10.1016/j.molcata.2016.01.024