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Diphosphines Possessing Electronically Different Donor Groups: Synthesis and Coordination Chemistry of the Unsymmetrical Di(N-pyrrolyl)phosphino-Functionalized dppm Analogue Ph[sub 2]PCH[sub 2]P(CN[sub 4]H[sub 4])[sub 2].

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Title: Diphosphines Possessing Electronically Different Donor Groups: Synthesis and Coordination Chemistry of the Unsymmetrical Di(N-pyrrolyl)phosphino-Functionalized dppm Analogue Ph[sub 2]PCH[sub 2]P(CN[sub 4]H[sub 4])[sub 2].
Authors: Burrows, Andrew D.1 a.d.burrows@bath.ac.uk, Mahon, Mary F.1, Nolan, Steven P.1, Varrone, Maurizio1
Source: Inorganic Chemistry. 11/3/2003, Vol. 42 Issue 22, p7227-7238. 12p. 11 Diagrams, 8 Charts.
Subjects: Phosphorus compounds, Ligands (Chemistry), Coordination compounds
Abstract: Studies the unsymmetrical diphoshinomethane ligand Ph[sub 2]PCH[sub 2]P(NC[sub 4]H[sub 4])sub 2 prepared from the reaction of Ph[sub 2]P-CH[sub 2]Li with PCl(NC[sub 4]H[sub 4])[sub 2]. Oxidation of the diphenylphosphino group with sulfur; Coordination chemistry; Pd-P bond; Molecular structure; Reactivity of the compound.
Database: Engineering Source
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Abstract:Studies the unsymmetrical diphoshinomethane ligand Ph[sub 2]PCH[sub 2]P(NC[sub 4]H[sub 4])sub 2 prepared from the reaction of Ph[sub 2]P-CH[sub 2]Li with PCl(NC[sub 4]H[sub 4])[sub 2]. Oxidation of the diphenylphosphino group with sulfur; Coordination chemistry; Pd-P bond; Molecular structure; Reactivity of the compound.
ISSN:00201669
DOI:10.1021/ic034487z