Bibliographic Details
| Title: |
Anion-templated 2D frameworks from hexahydroxytriphenylene. |
| Authors: |
Morshedi, Mahbod1, Willis, Anthony C.1, White, Nicholas G.1 |
| Source: |
CrystEngComm. 6/21/2016, Vol. 18 Issue 23, p4281-4284. 4p. |
| Subjects: |
Anion analysis, Phenylene compounds, Chemical templates, Hydroxides, Hydrogen bonding |
| Abstract: |
Hexahydroxytriphenylene (HHTP) forms 2D frameworks through O–H…anion hydrogen bonds with a range of anions. In all cases, 1 : 1 co-crystals of HHTP and tetraalkylammonium·anion salts are obtained, which have a layered 2D structure. When HSO4− was used as anion, an unprecedented methylation reaction was observed giving crystals containing the methylsulfate anion (MeOSO3−). [ABSTRACT FROM AUTHOR] |
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| Database: |
Engineering Source |
