Anion-templated 2D frameworks from hexahydroxytriphenylene.

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Title: Anion-templated 2D frameworks from hexahydroxytriphenylene.
Authors: Morshedi, Mahbod1, Willis, Anthony C.1, White, Nicholas G.1
Source: CrystEngComm. 6/21/2016, Vol. 18 Issue 23, p4281-4284. 4p.
Subjects: Anion analysis, Phenylene compounds, Chemical templates, Hydroxides, Hydrogen bonding
Abstract: Hexahydroxytriphenylene (HHTP) forms 2D frameworks through O–H…anion hydrogen bonds with a range of anions. In all cases, 1 : 1 co-crystals of HHTP and tetraalkylammonium·anion salts are obtained, which have a layered 2D structure. When HSO4− was used as anion, an unprecedented methylation reaction was observed giving crystals containing the methylsulfate anion (MeOSO3−). [ABSTRACT FROM AUTHOR]
Copyright of CrystEngComm is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Anion-templated 2D frameworks from hexahydroxytriphenylene.
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  Data: <searchLink fieldCode="JN" term="%22CrystEngComm%22">CrystEngComm</searchLink>. 6/21/2016, Vol. 18 Issue 23, p4281-4284. 4p.
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  Data: <searchLink fieldCode="DE" term="%22Anion+analysis%22">Anion analysis</searchLink><br /><searchLink fieldCode="DE" term="%22Phenylene+compounds%22">Phenylene compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Chemical+templates%22">Chemical templates</searchLink><br /><searchLink fieldCode="DE" term="%22Hydroxides%22">Hydroxides</searchLink><br /><searchLink fieldCode="DE" term="%22Hydrogen+bonding%22">Hydrogen bonding</searchLink>
– Name: Abstract
  Label: Abstract
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  Data: Hexahydroxytriphenylene (HHTP) forms 2D frameworks through O–H…anion hydrogen bonds with a range of anions. In all cases, 1 : 1 co-crystals of HHTP and tetraalkylammonium·anion salts are obtained, which have a layered 2D structure. When HSO4− was used as anion, an unprecedented methylation reaction was observed giving crystals containing the methylsulfate anion (MeOSO3−). [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of CrystEngComm is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1039/c6ce00297h
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        Type: general
      – SubjectFull: Phenylene compounds
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      – SubjectFull: Chemical templates
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      – SubjectFull: Hydroxides
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      – SubjectFull: Hydrogen bonding
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      – TitleFull: Anion-templated 2D frameworks from hexahydroxytriphenylene.
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              Text: 6/21/2016
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