The KA2 coupling reaction under green, solventless, heterogeneous catalysis.
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| Title: | The KA2 coupling reaction under green, solventless, heterogeneous catalysis. |
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| Authors: | Bosica, Giovanna1 giovanna.bosica@um.edu.mt, Abdilla, Roderick1 |
| Source: | Journal of Molecular Catalysis A: Chemistry. Jan2017 Part B, Vol. 426, p542-549. 8p. |
| Subjects: | Coupling reactions (Chemistry), Heterogeneous catalysis, Secondary amines, Catalysts recycling, Chemical reactions |
| Abstract: | Amberlyst A-21 supported CuI was found to be highly efficient novel heterogeneous catalyst for the three-component reaction between ketones, amines and alkynes, commonly called KA 2 -coupling. This inexpensive, easy-to-prepare, simple and recyclable catalyst has been employed in solventless conditions in the KA 2 coupling reaction involving both primary and secondary amines, ketones and various alkynes. The secondary and tertiary propargylamine products were obtained in good to excellent results in moderate reaction times. [ABSTRACT FROM AUTHOR] |
| Copyright of Journal of Molecular Catalysis A: Chemistry is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
| Database: | Engineering Source |
| FullText | Text: Availability: 0 |
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| Header | DbId: egs DbLabel: Engineering Source An: 120142606 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
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| Items | – Name: Title Label: Title Group: Ti Data: The KA2 coupling reaction under green, solventless, heterogeneous catalysis. – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22Bosica%2C+Giovanna%22">Bosica, Giovanna</searchLink><relatesTo>1</relatesTo><i> giovanna.bosica@um.edu.mt</i><br /><searchLink fieldCode="AR" term="%22Abdilla%2C+Roderick%22">Abdilla, Roderick</searchLink><relatesTo>1</relatesTo> – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22Journal+of+Molecular+Catalysis+A%3A+Chemistry%22">Journal of Molecular Catalysis A: Chemistry</searchLink>. Jan2017 Part B, Vol. 426, p542-549. 8p. – Name: Subject Label: Subjects Group: Su Data: <searchLink fieldCode="DE" term="%22Coupling+reactions+%28Chemistry%29%22">Coupling reactions (Chemistry)</searchLink><br /><searchLink fieldCode="DE" term="%22Heterogeneous+catalysis%22">Heterogeneous catalysis</searchLink><br /><searchLink fieldCode="DE" term="%22Secondary+amines%22">Secondary amines</searchLink><br /><searchLink fieldCode="DE" term="%22Catalysts+recycling%22">Catalysts recycling</searchLink><br /><searchLink fieldCode="DE" term="%22Chemical+reactions%22">Chemical reactions</searchLink> – Name: Abstract Label: Abstract Group: Ab Data: Amberlyst A-21 supported CuI was found to be highly efficient novel heterogeneous catalyst for the three-component reaction between ketones, amines and alkynes, commonly called KA 2 -coupling. This inexpensive, easy-to-prepare, simple and recyclable catalyst has been employed in solventless conditions in the KA 2 coupling reaction involving both primary and secondary amines, ketones and various alkynes. The secondary and tertiary propargylamine products were obtained in good to excellent results in moderate reaction times. [ABSTRACT FROM AUTHOR] – Name: AbstractSuppliedCopyright Label: Group: Ab Data: <i>Copyright of Journal of Molecular Catalysis A: Chemistry is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.) |
| PLink | https://search.ebscohost.com/login.aspx?direct=true&site=eds-live&db=egs&AN=120142606 |
| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.1016/j.molcata.2016.09.028 Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 8 StartPage: 542 Subjects: – SubjectFull: Coupling reactions (Chemistry) Type: general – SubjectFull: Heterogeneous catalysis Type: general – SubjectFull: Secondary amines Type: general – SubjectFull: Catalysts recycling Type: general – SubjectFull: Chemical reactions Type: general Titles: – TitleFull: The KA2 coupling reaction under green, solventless, heterogeneous catalysis. Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Bosica, Giovanna – PersonEntity: Name: NameFull: Abdilla, Roderick IsPartOfRelationships: – BibEntity: Dates: – D: 02 M: 01 Text: Jan2017 Part B Type: published Y: 2017 Identifiers: – Type: issn-print Value: 13811169 Numbering: – Type: volume Value: 426 Titles: – TitleFull: Journal of Molecular Catalysis A: Chemistry Type: main |
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