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Spectrophotometric and electrochemical determination of the formation constants of the complexes Curcumin–Fe(III)–water and Curcumin–Fe(II)–water

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Title: Spectrophotometric and electrochemical determination of the formation constants of the complexes Curcumin–Fe(III)–water and Curcumin–Fe(II)–water
Authors: Bernabé-Pineda, Marganta1, Ramírez-Silva, Maria Teresa1, Romero-Romo, Mario Alberto2, González-Vergara, Enrique3, Rojas-Hernández, Alberto1 suemi918@xanum.uam.mx
Source: Spectrochimica Acta Part A: Molecular & Biomolecular Spectroscopy. Apr2004, Vol. 60 Issue 5, p1105. 9p.
Subjects: Iron, Spectrum analysis, Voltammetry, Chemical reactions, Chemicals, Ions
Abstract: The formation of complexes among the Curcumin, Fe(III) and Fe(II) was studied in aqueous media within the 5–11 pH range by means of UV-Vis spectrophotometry and cyclic voltammetry. When the reaction between the Curcumin and the ions present in basic media took place, the resulting spectra of the systems Curcumin–Fe(III) and Curcumin–Fe(II) presented a similar behaviour. The cyclic voltammograms in basic media indicated that a chemical reaction has taken place between the Curcumin and Fe(III) before that of the formation of complexes. Data processing with SQUAD permitted to calculate the formation constants of the complexes Curcumin–Fe(III), corresponding to the species FeCur (log β1 1 0=22.25±0.03) and FeCur(OH)− (log β1 1-1=12.14±0.03), while for the complexes Curcumin–Fe(II) the corresponding formation constants of the species FeCur− (log β1 1 0=9.20±0.04), FeHCur (log β1 1 1=19.76±0.03), FeH2Cur+ (log β1 1 2=28.11±0.02). [Copyright &y& Elsevier]
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Database: Engineering Source
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Abstract:The formation of complexes among the Curcumin, Fe(III) and Fe(II) was studied in aqueous media within the 5–11 pH range by means of UV-Vis spectrophotometry and cyclic voltammetry. When the reaction between the Curcumin and the ions present in basic media took place, the resulting spectra of the systems Curcumin–Fe(III) and Curcumin–Fe(II) presented a similar behaviour. The cyclic voltammograms in basic media indicated that a chemical reaction has taken place between the Curcumin and Fe(III) before that of the formation of complexes. Data processing with SQUAD permitted to calculate the formation constants of the complexes Curcumin–Fe(III), corresponding to the species FeCur (<F>log β1 1 0=22.25±0.03</F>) and FeCur(OH)− (<F>log β1 1-1=12.14±0.03</F>), while for the complexes Curcumin–Fe(II) the corresponding formation constants of the species FeCur− (<F>log β1 1 0=9.20±0.04</F>), FeHCur (<F>log β1 1 1=19.76±0.03</F>), FeH2Cur+ (<F>log β1 1 2=28.11±0.02</F>). [Copyright &y& Elsevier]
ISSN:13861425
DOI:10.1016/S1386-1425(03)00344-5