Bibliographic Details
| Title: |
Metal-free trifluoromethylthiolation of arenediazonium salts with Me4NSCF3. |
| Authors: |
Bertoli, Giulia1, Exner, Benjamin1, Evers, Mathies V.2, Tschulik, Kristina2, Gooßen, Lukas J.1 lukas.goossen@rub.de |
| Source: |
Journal of Fluorine Chemistry. Jun2018, Vol. 210, p132-136. 5p. |
| Subjects: |
Diazonium compounds, Sulfides, Chemical reactions, Chemical synthesis, Electrochemical analysis |
| Abstract: |
A metal-free entry to the pharmaceutically meaningful substrate class of trifluoromethyl thioethers has been developed starting from widely available arenediazonium salts and commercially available Me 4 N + SCF 3 − . This reaction proceeds within one hour at 0 °C and is applicable to a wide range of functionalized substrates. [ABSTRACT FROM AUTHOR] |
|
Copyright of Journal of Fluorine Chemistry is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) |
| Database: |
Engineering Source |
