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Metal-free trifluoromethylthiolation of arenediazonium salts with Me4NSCF3.

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Title: Metal-free trifluoromethylthiolation of arenediazonium salts with Me4NSCF3.
Authors: Bertoli, Giulia1, Exner, Benjamin1, Evers, Mathies V.2, Tschulik, Kristina2, Gooßen, Lukas J.1 lukas.goossen@rub.de
Source: Journal of Fluorine Chemistry. Jun2018, Vol. 210, p132-136. 5p.
Subjects: Diazonium compounds, Sulfides, Chemical reactions, Chemical synthesis, Electrochemical analysis
Abstract: A metal-free entry to the pharmaceutically meaningful substrate class of trifluoromethyl thioethers has been developed starting from widely available arenediazonium salts and commercially available Me 4 N + SCF 3 − . This reaction proceeds within one hour at 0 °C and is applicable to a wide range of functionalized substrates. [ABSTRACT FROM AUTHOR]
Copyright of Journal of Fluorine Chemistry is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
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Header DbId: egs
DbLabel: Engineering Source
An: 129095031
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
PreciseRelevancyScore: 0
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  Data: Metal-free trifluoromethylthiolation of arenediazonium salts with Me4NSCF3.
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  Data: <searchLink fieldCode="AR" term="%22Bertoli%2C+Giulia%22">Bertoli, Giulia</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Exner%2C+Benjamin%22">Exner, Benjamin</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Evers%2C+Mathies+V%2E%22">Evers, Mathies V.</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22Tschulik%2C+Kristina%22">Tschulik, Kristina</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22Gooßen%2C+Lukas+J%2E%22">Gooßen, Lukas J.</searchLink><relatesTo>1</relatesTo><i> lukas.goossen@rub.de</i>
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  Data: <searchLink fieldCode="JN" term="%22Journal+of+Fluorine+Chemistry%22">Journal of Fluorine Chemistry</searchLink>. Jun2018, Vol. 210, p132-136. 5p.
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  Data: <searchLink fieldCode="DE" term="%22Diazonium+compounds%22">Diazonium compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Sulfides%22">Sulfides</searchLink><br /><searchLink fieldCode="DE" term="%22Chemical+reactions%22">Chemical reactions</searchLink><br /><searchLink fieldCode="DE" term="%22Chemical+synthesis%22">Chemical synthesis</searchLink><br /><searchLink fieldCode="DE" term="%22Electrochemical+analysis%22">Electrochemical analysis</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: A metal-free entry to the pharmaceutically meaningful substrate class of trifluoromethyl thioethers has been developed starting from widely available arenediazonium salts and commercially available Me 4 N + SCF 3 − . This reaction proceeds within one hour at 0 °C and is applicable to a wide range of functionalized substrates. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Journal of Fluorine Chemistry is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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      – Type: doi
        Value: 10.1016/j.jfluchem.2018.03.011
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      – Code: eng
        Text: English
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        PageCount: 5
        StartPage: 132
    Subjects:
      – SubjectFull: Diazonium compounds
        Type: general
      – SubjectFull: Sulfides
        Type: general
      – SubjectFull: Chemical reactions
        Type: general
      – SubjectFull: Chemical synthesis
        Type: general
      – SubjectFull: Electrochemical analysis
        Type: general
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      – TitleFull: Metal-free trifluoromethylthiolation of arenediazonium salts with Me4NSCF3.
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            NameFull: Bertoli, Giulia
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            NameFull: Exner, Benjamin
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            NameFull: Evers, Mathies V.
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            NameFull: Tschulik, Kristina
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            NameFull: Gooßen, Lukas J.
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            – D: 01
              M: 06
              Text: Jun2018
              Type: published
              Y: 2018
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              Value: 210
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