Bibliographic Details
| Title: |
Driving NHC organocatalysis on water through hydrophobic hydration for the synthesis of diverse heterocycles and carbocycles. |
| Authors: |
Suresh, Pavithira1, Thamotharan, Subbiah2, Ganesan, Subramaniapillai Selva1 selva@biotech.sastra.edu |
| Source: |
Catalysis Communications. Jun2018, Vol. 111, p47-51. 5p. |
| Subjects: |
Organocatalysis, Hydrophobic compounds, Hydration, Heterocyclic compounds, Butyrolactones, Deuterium oxide |
| Abstract: |
Unprecedented acceleration in the rate of the N -heterocyclic carbene (NHC) organocatalysis was observed while performing the reaction in water medium with NaCl as an additive during the synthesis of diverse spirooxindole-γ-butyrolactone derivatives. The seminal role of hydrophobic hydration effect for the acceleration of the reaction was further proved by performing the reaction with antihydrophobic additive LiClO 4 and using denser D 2 O solvent. [ABSTRACT FROM AUTHOR] |
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| Database: |
Engineering Source |
