Driving NHC organocatalysis on water through hydrophobic hydration for the synthesis of diverse heterocycles and carbocycles.
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| Title: | Driving NHC organocatalysis on water through hydrophobic hydration for the synthesis of diverse heterocycles and carbocycles. |
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| Authors: | Suresh, Pavithira1, Thamotharan, Subbiah2, Ganesan, Subramaniapillai Selva1 selva@biotech.sastra.edu |
| Source: | Catalysis Communications. Jun2018, Vol. 111, p47-51. 5p. |
| Subjects: | Organocatalysis, Hydrophobic compounds, Hydration, Heterocyclic compounds, Butyrolactones, Deuterium oxide |
| Abstract: | Unprecedented acceleration in the rate of the N -heterocyclic carbene (NHC) organocatalysis was observed while performing the reaction in water medium with NaCl as an additive during the synthesis of diverse spirooxindole-γ-butyrolactone derivatives. The seminal role of hydrophobic hydration effect for the acceleration of the reaction was further proved by performing the reaction with antihydrophobic additive LiClO 4 and using denser D 2 O solvent. [ABSTRACT FROM AUTHOR] |
| Copyright of Catalysis Communications is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
| Database: | Engineering Source |
| FullText | Text: Availability: 0 |
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| Header | DbId: egs DbLabel: Engineering Source An: 129295145 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
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| Items | – Name: Title Label: Title Group: Ti Data: Driving NHC organocatalysis on water through hydrophobic hydration for the synthesis of diverse heterocycles and carbocycles. – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22Suresh%2C+Pavithira%22">Suresh, Pavithira</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Thamotharan%2C+Subbiah%22">Thamotharan, Subbiah</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22Ganesan%2C+Subramaniapillai+Selva%22">Ganesan, Subramaniapillai Selva</searchLink><relatesTo>1</relatesTo><i> selva@biotech.sastra.edu</i> – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22Catalysis+Communications%22">Catalysis Communications</searchLink>. Jun2018, Vol. 111, p47-51. 5p. – Name: Subject Label: Subjects Group: Su Data: <searchLink fieldCode="DE" term="%22Organocatalysis%22">Organocatalysis</searchLink><br /><searchLink fieldCode="DE" term="%22Hydrophobic+compounds%22">Hydrophobic compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Hydration%22">Hydration</searchLink><br /><searchLink fieldCode="DE" term="%22Heterocyclic+compounds%22">Heterocyclic compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Butyrolactones%22">Butyrolactones</searchLink><br /><searchLink fieldCode="DE" term="%22Deuterium+oxide%22">Deuterium oxide</searchLink> – Name: Abstract Label: Abstract Group: Ab Data: Unprecedented acceleration in the rate of the N -heterocyclic carbene (NHC) organocatalysis was observed while performing the reaction in water medium with NaCl as an additive during the synthesis of diverse spirooxindole-γ-butyrolactone derivatives. The seminal role of hydrophobic hydration effect for the acceleration of the reaction was further proved by performing the reaction with antihydrophobic additive LiClO 4 and using denser D 2 O solvent. [ABSTRACT FROM AUTHOR] – Name: AbstractSuppliedCopyright Label: Group: Ab Data: <i>Copyright of Catalysis Communications is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.) |
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| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.1016/j.catcom.2018.03.024 Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 5 StartPage: 47 Subjects: – SubjectFull: Organocatalysis Type: general – SubjectFull: Hydrophobic compounds Type: general – SubjectFull: Hydration Type: general – SubjectFull: Heterocyclic compounds Type: general – SubjectFull: Butyrolactones Type: general – SubjectFull: Deuterium oxide Type: general Titles: – TitleFull: Driving NHC organocatalysis on water through hydrophobic hydration for the synthesis of diverse heterocycles and carbocycles. Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Suresh, Pavithira – PersonEntity: Name: NameFull: Thamotharan, Subbiah – PersonEntity: Name: NameFull: Ganesan, Subramaniapillai Selva IsPartOfRelationships: – BibEntity: Dates: – D: 01 M: 06 Text: Jun2018 Type: published Y: 2018 Identifiers: – Type: issn-print Value: 15667367 Numbering: – Type: volume Value: 111 Titles: – TitleFull: Catalysis Communications Type: main |
| ResultId | 1 |
