Bibliographic Details
| Title: |
Unprecedented pentanuclear mixed-valence Pt(II)-Pt(IV) complex anion in Q2[Pt5Cl20] salts (Q = TBA, PPN). |
| Authors: |
Belli Dell'Amico, Daniela1, Labella, Luca1, Marchetti, Fabio1, Ramello, Stefano1, Samaritani, Simona1 |
| Source: |
Inorganic Chemistry Communications. Sep2018, Vol. 95, p167-169. 3p. |
| Subjects: |
Platinum, Valence (Chemistry), Complex compounds, Crystal structure, X-ray diffraction measurement |
| Abstract: |
Red crystals of [TBA] 2 [Pt 5 Cl 20 ] were obtained by reacting [TBA] 2 [PtCl 6 ] with an excess of AlCl 3 at room temperature in CH 2 Cl 2 . The salt [PPN] 2 [Pt 5 Cl 20 ] containing the same anion was prepared by reaction of platinum tetrachloride with a small excess of [PPN]Cl in 1,2-dichloroethane at room temperature. Single crystal X-Ray diffraction studies confirmed that both species contained the mixed-valence [Pt 5 Cl 20 ] 2− anion with two dinuclear platinum (IV) Pt 2 Cl 10 fragments organized around a central square planar platinum (II) in a chair arrangement. [ABSTRACT FROM AUTHOR] |
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| Database: |
Engineering Source |
