Unprecedented pentanuclear mixed-valence Pt(II)-Pt(IV) complex anion in Q2[Pt5Cl20] salts (Q = TBA, PPN).
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| Title: | Unprecedented pentanuclear mixed-valence Pt(II)-Pt(IV) complex anion in Q2[Pt5Cl20] salts (Q = TBA, PPN). |
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| Authors: | Belli Dell'Amico, Daniela1, Labella, Luca1, Marchetti, Fabio1, Ramello, Stefano1, Samaritani, Simona1 |
| Source: | Inorganic Chemistry Communications. Sep2018, Vol. 95, p167-169. 3p. |
| Subjects: | Platinum, Valence (Chemistry), Complex compounds, Crystal structure, X-ray diffraction measurement |
| Abstract: | Red crystals of [TBA] 2 [Pt 5 Cl 20 ] were obtained by reacting [TBA] 2 [PtCl 6 ] with an excess of AlCl 3 at room temperature in CH 2 Cl 2 . The salt [PPN] 2 [Pt 5 Cl 20 ] containing the same anion was prepared by reaction of platinum tetrachloride with a small excess of [PPN]Cl in 1,2-dichloroethane at room temperature. Single crystal X-Ray diffraction studies confirmed that both species contained the mixed-valence [Pt 5 Cl 20 ] 2− anion with two dinuclear platinum (IV) Pt 2 Cl 10 fragments organized around a central square planar platinum (II) in a chair arrangement. [ABSTRACT FROM AUTHOR] |
| Copyright of Inorganic Chemistry Communications is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
| Database: | Engineering Source |
| FullText | Text: Availability: 0 |
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| Header | DbId: egs DbLabel: Engineering Source An: 131091517 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
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| Items | – Name: Title Label: Title Group: Ti Data: Unprecedented pentanuclear mixed-valence Pt(II)-Pt(IV) complex anion in Q2[Pt5Cl20] salts (Q = TBA, PPN). – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22Belli+Dell'Amico%2C+Daniela%22">Belli Dell'Amico, Daniela</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Labella%2C+Luca%22">Labella, Luca</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Marchetti%2C+Fabio%22">Marchetti, Fabio</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Ramello%2C+Stefano%22">Ramello, Stefano</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Samaritani%2C+Simona%22">Samaritani, Simona</searchLink><relatesTo>1</relatesTo> – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22Inorganic+Chemistry+Communications%22">Inorganic Chemistry Communications</searchLink>. Sep2018, Vol. 95, p167-169. 3p. – Name: Subject Label: Subjects Group: Su Data: <searchLink fieldCode="DE" term="%22Platinum%22">Platinum</searchLink><br /><searchLink fieldCode="DE" term="%22Valence+%28Chemistry%29%22">Valence (Chemistry)</searchLink><br /><searchLink fieldCode="DE" term="%22Complex+compounds%22">Complex compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Crystal+structure%22">Crystal structure</searchLink><br /><searchLink fieldCode="DE" term="%22X-ray+diffraction+measurement%22">X-ray diffraction measurement</searchLink> – Name: Abstract Label: Abstract Group: Ab Data: Red crystals of [TBA] 2 [Pt 5 Cl 20 ] were obtained by reacting [TBA] 2 [PtCl 6 ] with an excess of AlCl 3 at room temperature in CH 2 Cl 2 . The salt [PPN] 2 [Pt 5 Cl 20 ] containing the same anion was prepared by reaction of platinum tetrachloride with a small excess of [PPN]Cl in 1,2-dichloroethane at room temperature. Single crystal X-Ray diffraction studies confirmed that both species contained the mixed-valence [Pt 5 Cl 20 ] 2− anion with two dinuclear platinum (IV) Pt 2 Cl 10 fragments organized around a central square planar platinum (II) in a chair arrangement. [ABSTRACT FROM AUTHOR] – Name: AbstractSuppliedCopyright Label: Group: Ab Data: <i>Copyright of Inorganic Chemistry Communications is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.) |
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| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.1016/j.inoche.2018.07.034 Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 3 StartPage: 167 Subjects: – SubjectFull: Platinum Type: general – SubjectFull: Valence (Chemistry) Type: general – SubjectFull: Complex compounds Type: general – SubjectFull: Crystal structure Type: general – SubjectFull: X-ray diffraction measurement Type: general Titles: – TitleFull: Unprecedented pentanuclear mixed-valence Pt(II)-Pt(IV) complex anion in Q2[Pt5Cl20] salts (Q = TBA, PPN). Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Belli Dell'Amico, Daniela – PersonEntity: Name: NameFull: Labella, Luca – PersonEntity: Name: NameFull: Marchetti, Fabio – PersonEntity: Name: NameFull: Ramello, Stefano – PersonEntity: Name: NameFull: Samaritani, Simona IsPartOfRelationships: – BibEntity: Dates: – D: 01 M: 09 Text: Sep2018 Type: published Y: 2018 Identifiers: – Type: issn-print Value: 13877003 Numbering: – Type: volume Value: 95 Titles: – TitleFull: Inorganic Chemistry Communications Type: main |
| ResultId | 1 |
