Transparency, ultraviolet transmittance, and miscibility of poly(lactic acid)/poly(methyl methacrylate) blends.

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Bibliographic Details
Title: Transparency, ultraviolet transmittance, and miscibility of poly(lactic acid)/poly(methyl methacrylate) blends.
Authors: Teoh, E. L.1, Chow, W. S.1 shyang@usm.my
Source: Journal of Elastomers & Plastics. Nov2018, Vol. 50 Issue 7, p596-610. 15p.
Subjects: Transparencies, Methyl methacrylate, Dynamic mechanical analysis, Polymer blends, Ultraviolet radiation
Abstract: Poly(lactic acid)/poly(methyl methacrylate) (PLA/PMMA) blends were prepared by melt compounding technique. The miscibility of PLA/PMMA blends at various blending ratios (i.e. 80/20, 60/40, 40/60, and 20/80) was investigated using a dynamic mechanical analyzer (DMA) and solvent uptake experiment. The solvent uptake experiment was conducted to estimate the interaction of PLA/PMMA blends based on the calculation of Flory–Huggins interaction parameter (χ12). DMA results revealed that only single glass transition temperature (Tg) existed along the PLA/PMMA blends. Smallest χ12 (i.e. −0.03) was found on the PLA/PMMA20 blend, suggesting interaction between PLA and PMMA at this composition. The incorporation of PMMA slightly improved the UV protection properties of the PLA/PMMA blend, while maintaining their optical transparency. [ABSTRACT FROM AUTHOR]
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Database: Engineering Source
Description
Abstract:Poly(lactic acid)/poly(methyl methacrylate) (PLA/PMMA) blends were prepared by melt compounding technique. The miscibility of PLA/PMMA blends at various blending ratios (i.e. 80/20, 60/40, 40/60, and 20/80) was investigated using a dynamic mechanical analyzer (DMA) and solvent uptake experiment. The solvent uptake experiment was conducted to estimate the interaction of PLA/PMMA blends based on the calculation of Flory–Huggins interaction parameter (χ12). DMA results revealed that only single glass transition temperature (Tg) existed along the PLA/PMMA blends. Smallest χ12 (i.e. −0.03) was found on the PLA/PMMA20 blend, suggesting interaction between PLA and PMMA at this composition. The incorporation of PMMA slightly improved the UV protection properties of the PLA/PMMA blend, while maintaining their optical transparency. [ABSTRACT FROM AUTHOR]
ISSN:00952443
DOI:10.1177/0095244317743067