A thioether-containing luminescent metal-organic framework for highly selective and sensitive detection of Ag(I) ion.
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| Title: | A thioether-containing luminescent metal-organic framework for highly selective and sensitive detection of Ag(I) ion. |
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| Authors: | Liu, Jian-Jun1 (AUTHOR), Yu, Li-Mei1 (AUTHOR), Han, Fu-Xu1 (AUTHOR), Chen, Fu-Yu1 (AUTHOR), Cheng, Fei-Xiang1 (AUTHOR) chengfx2010@163.com |
| Source: | Journal of Solid State Chemistry. Feb2019, Vol. 270, p45-50. 6p. |
| Subjects: | Coordination polymers, Silver ions, Metal-organic frameworks, Luminescence quenching, X-ray powder diffraction, Flexible structures, Ethylene glycol |
| Abstract: | Abstract A stable three-dimensional coordination polymer, [Eu 2 (pbbp)(pbsd) 3 ] (1) (H 2 pbsd = 2,2′-((1,4-phenylenebis(methylene))bis(sulfanediyl))dinicotinic acid, H 2 pbbp·2Cl = 1,1′-(1,4-phenylene-bis(methylene))-bis(3-carboxy pyridinium) dichloride), was prepared by the solvothermal reaction of Eu(NO 3) 3 ·6H 2 O, H 2 pbbp·2Cl and H2pbsd in mixed solvent of DMF and H 2 O, which was characterized by single-crystal X-ray diffraction, powder X-ray diffraction, infrared spectroscopy, and thermogravimetric analyses. 1 exhibits a 3D 6-connected sqcl network decorated by uncoordinated Lewis basic thioether groups. In particular, 1 shows excellent application as luminescent sensor for sensing Ag+ ions in ethylene glycol solution with high sensitivity and selectivity based on luminescence quenching effect. Graphical abstract A stable three-dimensional coordination polymer with uncoordinated sites has been prepared by the solvothermal reaction, which exhibits a good selective and sensitive detection of Ag+ ions. fx1 Highlights • 3D structure with flexible carboxylate ligand. • The uncoordinated Lewis basic thioether groups within the pores of framework. • The Emission spectra of 1 exhibits the characteristic transition of Eu3+ ions. • Compound 1 exhibits good selective and sensitive for detection of Ag(I) ion. [ABSTRACT FROM AUTHOR] |
| Copyright of Journal of Solid State Chemistry is the property of Academic Press Inc. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
| Database: | Engineering Source |
| FullText | Text: Availability: 0 |
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| Header | DbId: egs DbLabel: Engineering Source An: 134299661 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
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| Items | – Name: Title Label: Title Group: Ti Data: A thioether-containing luminescent metal-organic framework for highly selective and sensitive detection of Ag(I) ion. – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22Liu%2C+Jian-Jun%22">Liu, Jian-Jun</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Yu%2C+Li-Mei%22">Yu, Li-Mei</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Han%2C+Fu-Xu%22">Han, Fu-Xu</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Chen%2C+Fu-Yu%22">Chen, Fu-Yu</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Cheng%2C+Fei-Xiang%22">Cheng, Fei-Xiang</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> chengfx2010@163.com</i> – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22Journal+of+Solid+State+Chemistry%22">Journal of Solid State Chemistry</searchLink>. Feb2019, Vol. 270, p45-50. 6p. – Name: Subject Label: Subjects Group: Su Data: <searchLink fieldCode="DE" term="%22Coordination+polymers%22">Coordination polymers</searchLink><br /><searchLink fieldCode="DE" term="%22Silver+ions%22">Silver ions</searchLink><br /><searchLink fieldCode="DE" term="%22Metal-organic+frameworks%22">Metal-organic frameworks</searchLink><br /><searchLink fieldCode="DE" term="%22Luminescence+quenching%22">Luminescence quenching</searchLink><br /><searchLink fieldCode="DE" term="%22X-ray+powder+diffraction%22">X-ray powder diffraction</searchLink><br /><searchLink fieldCode="DE" term="%22Flexible+structures%22">Flexible structures</searchLink><br /><searchLink fieldCode="DE" term="%22Ethylene+glycol%22">Ethylene glycol</searchLink> – Name: Abstract Label: Abstract Group: Ab Data: Abstract A stable three-dimensional coordination polymer, [Eu 2 (pbbp)(pbsd) 3 ] (1) (H 2 pbsd = 2,2′-((1,4-phenylenebis(methylene))bis(sulfanediyl))dinicotinic acid, H 2 pbbp·2Cl = 1,1′-(1,4-phenylene-bis(methylene))-bis(3-carboxy pyridinium) dichloride), was prepared by the solvothermal reaction of Eu(NO 3) 3 ·6H 2 O, H 2 pbbp·2Cl and H2pbsd in mixed solvent of DMF and H 2 O, which was characterized by single-crystal X-ray diffraction, powder X-ray diffraction, infrared spectroscopy, and thermogravimetric analyses. 1 exhibits a 3D 6-connected sqcl network decorated by uncoordinated Lewis basic thioether groups. In particular, 1 shows excellent application as luminescent sensor for sensing Ag+ ions in ethylene glycol solution with high sensitivity and selectivity based on luminescence quenching effect. Graphical abstract A stable three-dimensional coordination polymer with uncoordinated sites has been prepared by the solvothermal reaction, which exhibits a good selective and sensitive detection of Ag+ ions. fx1 Highlights • 3D structure with flexible carboxylate ligand. • The uncoordinated Lewis basic thioether groups within the pores of framework. • The Emission spectra of 1 exhibits the characteristic transition of Eu3+ ions. • Compound 1 exhibits good selective and sensitive for detection of Ag(I) ion. [ABSTRACT FROM AUTHOR] – Name: AbstractSuppliedCopyright Label: Group: Ab Data: <i>Copyright of Journal of Solid State Chemistry is the property of Academic Press Inc. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.) |
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| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.1016/j.jssc.2018.11.001 Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 6 StartPage: 45 Subjects: – SubjectFull: Coordination polymers Type: general – SubjectFull: Silver ions Type: general – SubjectFull: Metal-organic frameworks Type: general – SubjectFull: Luminescence quenching Type: general – SubjectFull: X-ray powder diffraction Type: general – SubjectFull: Flexible structures Type: general – SubjectFull: Ethylene glycol Type: general Titles: – TitleFull: A thioether-containing luminescent metal-organic framework for highly selective and sensitive detection of Ag(I) ion. Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Liu, Jian-Jun – PersonEntity: Name: NameFull: Yu, Li-Mei – PersonEntity: Name: NameFull: Han, Fu-Xu – PersonEntity: Name: NameFull: Chen, Fu-Yu – PersonEntity: Name: NameFull: Cheng, Fei-Xiang IsPartOfRelationships: – BibEntity: Dates: – D: 01 M: 02 Text: Feb2019 Type: published Y: 2019 Identifiers: – Type: issn-print Value: 00224596 Numbering: – Type: volume Value: 270 Titles: – TitleFull: Journal of Solid State Chemistry Type: main |
| ResultId | 1 |
