Bibliographic Details
| Title: |
Synthesis, structure and magnetic properties of a series of Ln(III) complexes with radical-anionic iminopyridine ligands: effect of lanthanide ions on the slow relaxation of the magnetization. |
| Authors: |
Long, Jérôme1 (AUTHOR) jerome.long@umontpellier.fr, Skvortsov, Grigorii G.2 (AUTHOR), Cherkasov, Anton V.2 (AUTHOR), Lyssenko, Konstantin A.3 (AUTHOR), Poddel'sky, Andrei I.2 (AUTHOR), Guari, Yannick1 (AUTHOR), Larionova, Joulia1 (AUTHOR), Trifonov, Alexander A.2,3 (AUTHOR) trif@iomc.ras.ru |
| Source: |
Dalton Transactions: An International Journal of Inorganic Chemistry. 8/28/2019, Vol. 48 Issue 32, p12018-12022. 5p. |
| Subjects: |
Magnetic structure, Magnetic properties, Magnetization, Magnetic anisotropy, Ligands (Chemistry), Ions, Relaxation for health |
| Abstract: |
We report the investigation of synthesis, structure and magnetic properties of a series of homoleptic Ln(III) complexes coordinated by radical-anionic iminopyridine ligands of general formula [Ln(IPy)3]·solv (IPy = iminopyridine; Ln = Tb, Dy, Er, Y, Gd). The dysprosium analogue exhibits a zero-field Single-Molecule Magnet (SMM) behavior. [ABSTRACT FROM AUTHOR] |
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| Database: |
Engineering Source |
