Bibliographic Details
| Title: |
Molecular Sn(II) precursors for room temperature deposition of crystalline elemental tin. |
| Authors: |
Bykowski, Janelle1 (AUTHOR), Sinclair, Jocelyn1 (AUTHOR), Trach, Jonathan1 (AUTHOR), Ferguson, Michael J.1 (AUTHOR), Rivard, Eric1 (AUTHOR) erivard@ualberta.ca |
| Source: |
Dalton Transactions: An International Journal of Inorganic Chemistry. 2/14/2023, Vol. 52 Issue 6, p1602-1607. 6p. |
| Subjects: |
Metathesis reactions, Hydrides, Temperature |
| Abstract: |
We report mild routes for the deposition of crystalline films of elemental tin via the formation and subsequent decomposition of unstable tin(II) hydrides. Specifically, we take advantage of efficient OtBu/H metathesis involving Sn(II) alkoxide precursors and the hydride source pinacolborane (HBpin); related -N(SiMe3)2/H exchange also afforded elemental tin as a final (insoluble) product. [ABSTRACT FROM AUTHOR] |
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| Database: |
Engineering Source |
