Molecular Sn(II) precursors for room temperature deposition of crystalline elemental tin.
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| Title: | Molecular Sn(II) precursors for room temperature deposition of crystalline elemental tin. |
|---|---|
| Authors: | Bykowski, Janelle1 (AUTHOR), Sinclair, Jocelyn1 (AUTHOR), Trach, Jonathan1 (AUTHOR), Ferguson, Michael J.1 (AUTHOR), Rivard, Eric1 (AUTHOR) erivard@ualberta.ca |
| Source: | Dalton Transactions: An International Journal of Inorganic Chemistry. 2/14/2023, Vol. 52 Issue 6, p1602-1607. 6p. |
| Subjects: | Metathesis reactions, Hydrides, Temperature |
| Abstract: | We report mild routes for the deposition of crystalline films of elemental tin via the formation and subsequent decomposition of unstable tin(II) hydrides. Specifically, we take advantage of efficient OtBu/H metathesis involving Sn(II) alkoxide precursors and the hydride source pinacolborane (HBpin); related -N(SiMe3)2/H exchange also afforded elemental tin as a final (insoluble) product. [ABSTRACT FROM AUTHOR] |
| Copyright of Dalton Transactions: An International Journal of Inorganic Chemistry is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
| Database: | Engineering Source |
| FullText | Text: Availability: 0 |
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| Header | DbId: egs DbLabel: Engineering Source An: 161741163 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
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| Items | – Name: Title Label: Title Group: Ti Data: Molecular Sn(II) precursors for room temperature deposition of crystalline elemental tin. – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22Bykowski%2C+Janelle%22">Bykowski, Janelle</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Sinclair%2C+Jocelyn%22">Sinclair, Jocelyn</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Trach%2C+Jonathan%22">Trach, Jonathan</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Ferguson%2C+Michael+J%2E%22">Ferguson, Michael J.</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Rivard%2C+Eric%22">Rivard, Eric</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> erivard@ualberta.ca</i> – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22Dalton+Transactions%3A+An+International+Journal+of+Inorganic+Chemistry%22">Dalton Transactions: An International Journal of Inorganic Chemistry</searchLink>. 2/14/2023, Vol. 52 Issue 6, p1602-1607. 6p. – Name: Subject Label: Subjects Group: Su Data: <searchLink fieldCode="DE" term="%22Metathesis+reactions%22">Metathesis reactions</searchLink><br /><searchLink fieldCode="DE" term="%22Hydrides%22">Hydrides</searchLink><br /><searchLink fieldCode="DE" term="%22Temperature%22">Temperature</searchLink> – Name: Abstract Label: Abstract Group: Ab Data: We report mild routes for the deposition of crystalline films of elemental tin via the formation and subsequent decomposition of unstable tin(II) hydrides. Specifically, we take advantage of efficient OtBu/H metathesis involving Sn(II) alkoxide precursors and the hydride source pinacolborane (HBpin); related -N(SiMe3)2/H exchange also afforded elemental tin as a final (insoluble) product. [ABSTRACT FROM AUTHOR] – Name: AbstractSuppliedCopyright Label: Group: Ab Data: <i>Copyright of Dalton Transactions: An International Journal of Inorganic Chemistry is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.) |
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| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.1039/d2dt04028j Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 6 StartPage: 1602 Subjects: – SubjectFull: Metathesis reactions Type: general – SubjectFull: Hydrides Type: general – SubjectFull: Temperature Type: general Titles: – TitleFull: Molecular Sn(II) precursors for room temperature deposition of crystalline elemental tin. Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Bykowski, Janelle – PersonEntity: Name: NameFull: Sinclair, Jocelyn – PersonEntity: Name: NameFull: Trach, Jonathan – PersonEntity: Name: NameFull: Ferguson, Michael J. – PersonEntity: Name: NameFull: Rivard, Eric IsPartOfRelationships: – BibEntity: Dates: – D: 14 M: 02 Text: 2/14/2023 Type: published Y: 2023 Identifiers: – Type: issn-print Value: 14779226 Numbering: – Type: volume Value: 52 – Type: issue Value: 6 Titles: – TitleFull: Dalton Transactions: An International Journal of Inorganic Chemistry Type: main |
| ResultId | 1 |
