Bibliographic Details
| Title: |
Cu4Ti4-oxo clusters functionalized by in situ – generated 2,2′-biphenolate ligands from the oxidative coupling of phenols. |
| Authors: |
Liu, Xiao-Xue1 (AUTHOR), Wang, Zi-Rui2 (AUTHOR), Chen, Guang-Hui2 (AUTHOR), Li, Qiao-Hong2 (AUTHOR), Tao, Jun1 (AUTHOR) taojun@bit.edu.cn, Zhang, Lei2 (AUTHOR) LZhang@fjirsm.ac.cn |
| Source: |
Dalton Transactions: An International Journal of Inorganic Chemistry. 2/21/2023, Vol. 52 Issue 7, p1857-1860. 4p. |
| Subjects: |
Oxidative coupling, Phenols, Phenol, Ligands (Chemistry), Copper, Bismuth compounds |
| Abstract: |
Herein, we report a twisted cubic Cu(I)4Ti(IV)4-oxo cluster stabilized by in situ – formed 2,2′-biphenolate ligands from the oxidative coupling of phenols. The 2,2′-biphenolate-functionalized Cu(I)4Ti(IV)4O4 cluster shows short Cu⋯C contacts and exhibits smaller HOMO–LUMO gaps than those of reported Ti(IV)4O4. [ABSTRACT FROM AUTHOR] |
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| Database: |
Engineering Source |
