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Cu4Ti4-oxo clusters functionalized by in situ – generated 2,2′-biphenolate ligands from the oxidative coupling of phenols.

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Title: Cu4Ti4-oxo clusters functionalized by in situ – generated 2,2′-biphenolate ligands from the oxidative coupling of phenols.
Authors: Liu, Xiao-Xue1 (AUTHOR), Wang, Zi-Rui2 (AUTHOR), Chen, Guang-Hui2 (AUTHOR), Li, Qiao-Hong2 (AUTHOR), Tao, Jun1 (AUTHOR) taojun@bit.edu.cn, Zhang, Lei2 (AUTHOR) LZhang@fjirsm.ac.cn
Source: Dalton Transactions: An International Journal of Inorganic Chemistry. 2/21/2023, Vol. 52 Issue 7, p1857-1860. 4p.
Subjects: Oxidative coupling, Phenols, Phenol, Ligands (Chemistry), Copper, Bismuth compounds
Abstract: Herein, we report a twisted cubic Cu(I)4Ti(IV)4-oxo cluster stabilized by in situ – formed 2,2′-biphenolate ligands from the oxidative coupling of phenols. The 2,2′-biphenolate-functionalized Cu(I)4Ti(IV)4O4 cluster shows short Cu⋯C contacts and exhibits smaller HOMO–LUMO gaps than those of reported Ti(IV)4O4. [ABSTRACT FROM AUTHOR]
Copyright of Dalton Transactions: An International Journal of Inorganic Chemistry is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
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Header DbId: egs
DbLabel: Engineering Source
An: 161876786
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
PreciseRelevancyScore: 0
IllustrationInfo
Items – Name: Title
  Label: Title
  Group: Ti
  Data: Cu<subscript>4</subscript>Ti<subscript>4</subscript>-oxo clusters functionalized by in situ – generated 2,2′-biphenolate ligands from the oxidative coupling of phenols.
– Name: Author
  Label: Authors
  Group: Au
  Data: <searchLink fieldCode="AR" term="%22Liu%2C+Xiao-Xue%22">Liu, Xiao-Xue</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Wang%2C+Zi-Rui%22">Wang, Zi-Rui</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Chen%2C+Guang-Hui%22">Chen, Guang-Hui</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Li%2C+Qiao-Hong%22">Li, Qiao-Hong</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Tao%2C+Jun%22">Tao, Jun</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> taojun@bit.edu.cn</i><br /><searchLink fieldCode="AR" term="%22Zhang%2C+Lei%22">Zhang, Lei</searchLink><relatesTo>2</relatesTo> (AUTHOR)<i> LZhang@fjirsm.ac.cn</i>
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  Group: Src
  Data: <searchLink fieldCode="JN" term="%22Dalton+Transactions%3A+An+International+Journal+of+Inorganic+Chemistry%22">Dalton Transactions: An International Journal of Inorganic Chemistry</searchLink>. 2/21/2023, Vol. 52 Issue 7, p1857-1860. 4p.
– Name: Subject
  Label: Subjects
  Group: Su
  Data: <searchLink fieldCode="DE" term="%22Oxidative+coupling%22">Oxidative coupling</searchLink><br /><searchLink fieldCode="DE" term="%22Phenols%22">Phenols</searchLink><br /><searchLink fieldCode="DE" term="%22Phenol%22">Phenol</searchLink><br /><searchLink fieldCode="DE" term="%22Ligands+%28Chemistry%29%22">Ligands (Chemistry)</searchLink><br /><searchLink fieldCode="DE" term="%22Copper%22">Copper</searchLink><br /><searchLink fieldCode="DE" term="%22Bismuth+compounds%22">Bismuth compounds</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Herein, we report a twisted cubic Cu(I)4Ti(IV)4-oxo cluster stabilized by in situ – formed 2,2′-biphenolate ligands from the oxidative coupling of phenols. The 2,2′-biphenolate-functionalized Cu(I)4Ti(IV)4O4 cluster shows short Cu⋯C contacts and exhibits smaller HOMO–LUMO gaps than those of reported Ti(IV)4O4. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Dalton Transactions: An International Journal of Inorganic Chemistry is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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      – Type: doi
        Value: 10.1039/d2dt03756d
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      – Code: eng
        Text: English
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        PageCount: 4
        StartPage: 1857
    Subjects:
      – SubjectFull: Oxidative coupling
        Type: general
      – SubjectFull: Phenols
        Type: general
      – SubjectFull: Phenol
        Type: general
      – SubjectFull: Ligands (Chemistry)
        Type: general
      – SubjectFull: Copper
        Type: general
      – SubjectFull: Bismuth compounds
        Type: general
    Titles:
      – TitleFull: Cu4Ti4-oxo clusters functionalized by in situ – generated 2,2′-biphenolate ligands from the oxidative coupling of phenols.
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          Name:
            NameFull: Liu, Xiao-Xue
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          Name:
            NameFull: Wang, Zi-Rui
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            NameFull: Chen, Guang-Hui
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            NameFull: Li, Qiao-Hong
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            NameFull: Tao, Jun
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            NameFull: Zhang, Lei
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            – D: 21
              M: 02
              Text: 2/21/2023
              Type: published
              Y: 2023
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              Value: 52
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              Value: 7
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            – TitleFull: Dalton Transactions: An International Journal of Inorganic Chemistry
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