The introduction of the disconnection approach into polymer synthesis.
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| Title: | The introduction of the disconnection approach into polymer synthesis. |
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| Authors: | Lu, Dawei1 (AUTHOR) 2390917007@qq.com, Zou, Xudong2 (AUTHOR), Ye, Liqin1 (AUTHOR) |
| Source: | Polymers for Advanced Technologies. Jul2023, Vol. 34 Issue 7, p2097-2116. 20p. |
| Subjects: | Polymerization, Organic chemistry, Covalent bonds, Polymer structure, Rate coefficients (Chemistry), Polymers |
| Abstract: | The disconnection approach, a widely utilized method of design synthesis route, has played crucial roles in contemporary organic chemistry for decades. Here, we provide an introduction to the construction of polymer main chains. The implementation of the strategy hinges on determining where to disconnect based on the successful polymerization reaction in order to infer a suitable monomer. By investigating specific covalent bonds and structures in polymers, several specific linkers are highlighted to demonstrate how to design and synthesize polymer main chains using reverse thinking, thus inspiring those in polymer synthesis. [ABSTRACT FROM AUTHOR] |
| Copyright of Polymers for Advanced Technologies is the property of Wiley-Blackwell and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
| Database: | Engineering Source |
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| Abstract: | The disconnection approach, a widely utilized method of design synthesis route, has played crucial roles in contemporary organic chemistry for decades. Here, we provide an introduction to the construction of polymer main chains. The implementation of the strategy hinges on determining where to disconnect based on the successful polymerization reaction in order to infer a suitable monomer. By investigating specific covalent bonds and structures in polymers, several specific linkers are highlighted to demonstrate how to design and synthesize polymer main chains using reverse thinking, thus inspiring those in polymer synthesis. [ABSTRACT FROM AUTHOR] |
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| ISSN: | 10427147 |
| DOI: | 10.1002/pat.6050 |
