Redistribution of incompatible elements during hydrothermal alteration of pegmatite from the Djurkovo Pb-Zn deposit, Central Rhodopes.

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Title: Redistribution of incompatible elements during hydrothermal alteration of pegmatite from the Djurkovo Pb-Zn deposit, Central Rhodopes.
Alternate Title: Преразпределение на несъвместими елементи при хидротермални изменения на пегматити от Pb-Zn находище Джурково, Централни Родопи.
Authors: Georgieva, Sylvina1 sylvina@geology.bas.bg, Vassileva, Rossitsa D.1 rosivas@geology.bas.bg, Grozdev, Valentin1 valgrozdev@gmail.com, Milenkov, Georgi1 georgimilenkov7@gmail.com, Cempírek, Jan2 jan.cempirek@gmail.com, Škoda, Radek2 rskoda@sci.muni.cz, Stefanova, Elitsa1 elitsa.s@gmail.com
Source: Review of the Bulgarian Geological Society. 2023, Vol. 84 Issue 3, p35-38. 4p.
Subjects: Hydrothermal alteration, Oxide minerals, Sphene, Garnet, Pegmatites, Minerals
Abstract: Mineralogical and geochemical study was done on weakly deformed, relatively thin pegmatites that intruded the marbles of the Rhodope metamorphic complex in the Djurkovo Pb-Zn deposit, Central Rhodopes. The pegmatites consist mainly of K-feldspar and quartz and contain minor garnet; the pegmatites lack clear zonation except for the preferable crystallization of the garnet in the central parts. The main accessory minerals are ishikawaite, zircon, monazite-(Ce), apatite, and titanite. The textural relationships indicate later hydrothermal alteration of pegmatites which led to the formation of albite, epidote, sericite, chlorite, carbonate, quartz and leucoxene. The (REE+Y, ACT, Nb, Ta, Ti)-bearing pegmatite minerals (oxides, silicates and phosphates) are partly leached and/or replaced by secondary ones. The newly-formed phases precipitated as anhedral grains along fractures and dissolved zones onto/ or close to the primary minerals due to the limited mobility of the incompatible elements in fluids conditioned by pH, ligand activity and temperature. [ABSTRACT FROM AUTHOR]
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Abstract:Mineralogical and geochemical study was done on weakly deformed, relatively thin pegmatites that intruded the marbles of the Rhodope metamorphic complex in the Djurkovo Pb-Zn deposit, Central Rhodopes. The pegmatites consist mainly of K-feldspar and quartz and contain minor garnet; the pegmatites lack clear zonation except for the preferable crystallization of the garnet in the central parts. The main accessory minerals are ishikawaite, zircon, monazite-(Ce), apatite, and titanite. The textural relationships indicate later hydrothermal alteration of pegmatites which led to the formation of albite, epidote, sericite, chlorite, carbonate, quartz and leucoxene. The (REE+Y, ACT, Nb, Ta, Ti)-bearing pegmatite minerals (oxides, silicates and phosphates) are partly leached and/or replaced by secondary ones. The newly-formed phases precipitated as anhedral grains along fractures and dissolved zones onto/ or close to the primary minerals due to the limited mobility of the incompatible elements in fluids conditioned by pH, ligand activity and temperature. [ABSTRACT FROM AUTHOR]
ISSN:00073938
DOI:10.52215/rev.bgs.2023.84.3.35