Rhenium Cluster Complexes with Polyborohydride Anions, [Re6S8(Me2PzH)6]X (X = B10H10, B12H12).
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| Title: | Rhenium Cluster Complexes with Polyborohydride Anions, [Re |
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| Authors: | Davydova, M. P.1 (AUTHOR), Sukhikh, T. S.1 (AUTHOR), Rakhmanova, M. I.1 (AUTHOR), Brylev, K. A.1 (AUTHOR), Artem'ev, A. V.1 (AUTHOR) chemisufarm@yandex.ru |
| Source: | Journal of Structural Chemistry. Jan2024, Vol. 65 Issue 1, p186-195. 10p. |
| Subjects: | Rhenium, Anions, Phosphorescence |
| Abstract: | Interaction of [Re6S8(Me2PzH)6]Br2 with K2B10H10 and (Et3NH)2B12H12 yields novel [Re6S8(Me2PzH)6][B10H10] (1) and [Re6S8(Me2PzH)6][B12H12] (2) hybrid compounds combining [Re6S8 (Me2PzH)6]2+ metal-cluster cations and [BnHn]2– polyborohydride cluster anions (n = 10, 12) in their structure. Crystals of the prepared compounds exhibit an ionic 3D supramolecular structure formed by short H–B⋯H–C contacts. At room temperature, these compounds exhibit red phosphorescence with λmax = 680 nm (1) and 670 nm (2), respectively. [ABSTRACT FROM AUTHOR] |
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| Database: | Engineering Source |
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| Abstract: | Interaction of [Re6S8(Me2PzH)6]Br2 with K2B10H10 and (Et3NH)2B12H12 yields novel [Re6S8(Me2PzH)6][B10H10] (1) and [Re6S8(Me2PzH)6][B12H12] (2) hybrid compounds combining [Re6S8 (Me2PzH)6]2+ metal-cluster cations and [BnHn]2– polyborohydride cluster anions (n = 10, 12) in their structure. Crystals of the prepared compounds exhibit an ionic 3D supramolecular structure formed by short H–B⋯H–C contacts. At room temperature, these compounds exhibit red phosphorescence with λmax = 680 nm (1) and 670 nm (2), respectively. [ABSTRACT FROM AUTHOR] |
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| ISSN: | 00224766 |
| DOI: | 10.1134/S0022476624010177 |
